Controlled generation of luminescent centers in hexagonal boron nitride by irradiation engineering

M. Fischer, J. M. Caridad, A. Sajid, S. Ghaderzadeh, M. Ghorbani-Asl, L. Gammelgaard, Peter Bøggild, Kristian Sommer Thygesen, A. V. Krasheninnikov, Sanshui Xiao, Martijn Wubs, Nicolas Stenger*

*Corresponding author for this work

Research output: Contribution to journalJournal articleResearchpeer-review

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Abstract

Irradiation engineering on hexagonal boron nitride reveals insights into the microscopic nature of quantum emitters. Luminescent centers in the two-dimensional material hexagonal boron nitride have the potential to enable quantum applications at room temperature. To be used for applications, it is crucial to generate these centers in a controlled manner and to identify their microscopic nature. Here, we present a method inspired by irradiation engineering with oxygen atoms. We systematically explore the influence of the kinetic energy and the irradiation fluence on the generation of luminescent centers. We find modifications of their density for both parameters, while a fivefold enhancement is observed with increasing fluence. Molecular dynamics simulations clarify the generation mechanism of these centers and their microscopic nature. We infer that VNCB and VB− are the most likely centers formed. Ab initio calculations of their optical properties show excellent agreement with our experiments. Our methodology generates quantum emitters in a controlled manner and provides insights into their microscopic nature.
Original languageEnglish
Article numbereabe7138
JournalScience Advances
Volume7
Issue number8
Number of pages8
ISSN2375-2548
DOIs
Publication statusPublished - 2021

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