Continuous Catalytic Hydrodeoxygenation of Guaiacol over Pt/SiO2 and Pt/H-MFI-90

Melanie Hellinger, Sina Baier, Peter Mølgaard Mortensen, Wolfgang Kleist, Anker Degn Jensen, Jan-Dierk Grunwaldt

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Abstract

Hydrodeoxygenation of guaiacol in the presence of 1-octanol was studied in a fixed-bed reactor under mild conditions (50–250 °C) over platinum particles supported on silica (Pt/SiO2) and a zeolite with framework type MFI at a Si/Al-ratio of 45 (Pt/H-MFI-90). The deoxygenation selectivity strongly depended on the support and the temperature. Both guaiacol and octanol were rapidly deoxygenated in the presence of hydrogen over Pt/H-MFI-90 at 250 °C to cyclohexane and octane, respectively. In contrast, Pt/SiO2 mostly showed hydrogenation, but hardly any deoxygenation activity. The acidic sites of the MFI-90 support lead to improved deoxygenation performance at the mild temperature conditions of this study. Significant conversions under reaction conditions applied already occurred at temperatures of 200 °C. However, during long-term stability tests, the Pt/H-MFI-90 catalyst deactivated after more than 30 h, probably due to carbon deposition, whereas Pt/SiO2 was more stable. The catalytic activity of the zeolite catalyst could only partly be regained by calcination in air, as some of the acidic sites were lost.
Original languageEnglish
JournalCatalysts
Volume5
Issue number3
Pages (from-to)1152-1166
ISSN2073-4344
DOIs
Publication statusPublished - 2015

Keywords

  • 1-octanol
  • Bio-oil upgrading
  • Continuous process
  • Guaiacol
  • Hydrodeoxygenation
  • Pt catalysts
  • Zeolites

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