Conjugated Polymers Via Direct Arylation Polymerization in Continuous Flow: Minimizing the Cost and Batch-to-Batch Variations for High-Throughput Energy Conversion

Nemal S. Gobalasingham, Jon Eggert Carlé, Frederik C Krebs, Barry C Thompson, Eva Bundgaard, Martin Helgesen

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

Continuous flow methods are utilized in conjunction with direct arylation polymerization (DArP) for the scaled synthesis of the roll-to-roll compatible polymer, poly[(2,5-bis(2-hexyldecyloxy)phenylene)-alt-(4,7-di(thiophen-2-yl)-benzo[c][1,2,5]thiadiazole)] (PPDTBT). PPDTBT is based on simple, inexpensive, and scalable monomers using thienyl-flanked benzothiadiazole as the acceptor, which is the first β-unprotected substrate to be used in continuous flow via DArP, enabling critical evaluation of the suitability of this emerging synthetic method for minimizing defects and for the scaled synthesis of high-performance materials. To demonstrate the usefulness of the method, DArP-prepared PPDTBT via continuous flow synthesis is employed for the preparation of indium tin oxide (ITO)-free and flexible roll-coated solar cells to achieve a power conversion efficiency of 3.5% for 1 cm2 devices, which is comparable to the performance of PPDTBT polymerized through Stille cross coupling. These efforts demonstrate the distinct advantages of the continuous flow protocol with DArP avoiding use of toxic tin chemicals, reducing the associated costs of polymer upscaling, and minimizing batch-to-batch variations for high-quality material.
Original languageEnglish
Article number1700526
JournalMacromolecular Rapid Communications
Volume38
Issue number22
Number of pages7
ISSN1022-1336
DOIs
Publication statusPublished - 2017

Keywords

  • Conjugated polymers
  • Continuous flow synthesis
  • Direct arylation polymerization
  • Organic solar cells

Fingerprint Dive into the research topics of 'Conjugated Polymers Via Direct Arylation Polymerization in Continuous Flow: Minimizing the Cost and Batch-to-Batch Variations for High-Throughput Energy Conversion'. Together they form a unique fingerprint.

Cite this