Conduvtivity, NMR, Thermal Measurements and Phase Diagram of the K2S2O7-KHSO4 System.

Kim Michael Eriksen, Rasmus Fehrmann, Gerard Hatem, Marcelle Gaune-Escard, Olga B. Lapina, Vladimir M. Mastikhin

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Abstract

The phase diagram of the catalytically important K2S2O7-KHSO4 molten salt solvent system has been investigated by electrochemical, thermal and spectroscopic methods.It is of the simple eutectic type with a temperature of fusion of 205C for the eutectic composition, X(KHSO4)= 0.94. The conductivities of the solid and molten K2S2O7-KHSO4 system were measured at 13 different compositions in the whole composition range, X(KHSO4)= 0-1. The conductivity of the molten mixtures were fitted to polynomia of the second degree.The results indicated delocalization of the conducting ions compared to the pure molten components.
Original languageEnglish
JournalJ. Phys. Chem.
Volume100
Issue number25
Pages (from-to)10771-10778
Publication statusPublished - 1996

Cite this

Eriksen, K. M., Fehrmann, R., Hatem, G., Gaune-Escard, M., Lapina, O. B., & Mastikhin, V. M. (1996). Conduvtivity, NMR, Thermal Measurements and Phase Diagram of the K2S2O7-KHSO4 System. J. Phys. Chem., 100(25), 10771-10778.