Comparison of additive amount used in spin-coated and roll-coated organic solar cells

Pei Cheng, Yuze Lin, Natalia Klaudia Zawacka, Thomas Rieks Andersen, Wenqing Liu, Eva Bundgaard, Mikkel Jørgensen, Hongzheng Chen, Frederik C Krebs, Xiaowei Zhan

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

All-polymer and polymer/fullerene inverted solar cells were fabricated by spin-coating and roll-coating processes. The spin-coated small-area (0.04 cm(2)) devices were fabricated on indium tin oxide (ITO) coated glass substrates in nitrogen. The roll-coated large-area (1.0 cm(2)) devices were prepared on ITO-free flexible substrates under ambient conditions. The use of a solvent additive, 1,8-diiodooctane (DIO), facilitated phase separation and enhanced power conversion efficiencies (PCEs). The PCE of polymer/fullerene solar cells increased from 4.58% to 8.12% with 2.5% (v/v) DIO when using the spin-coating process, and increased from 1.37% to 2.09% with 5% (v/v) DIO in the roll-coating process. The PCE of all-polymer solar cells increased from 1.44% to 3.51% with 4% (v/v) DIO when employing the spin-coating process. For the roll-coated large area devices the PCE increased from 0.15% to 0.73% with 9% (v/v) DIO. The optimal amounts of DIO, when using the roll-coating process for the two different active layers (5% and 9% respectively) are significantly higher than those for the spin-coating process (2.5% and 4%, respectively), which is ascribed to a fundamentally different drying mechanism.
Original languageEnglish
JournalJournal of Materials Chemistry A
Volume2
Issue number45
Pages (from-to)19542-19549
Number of pages8
ISSN2050-7488
DOIs
Publication statusPublished - 2014

Keywords

  • CHEMISTRY,
  • ENERGY
  • MATERIALS
  • BULK-HETEROJUNCTION
  • HIGH-PERFORMANCE
  • EFFICIENCY ENHANCEMENT
  • PHOTOVOLTAIC POLYMERS
  • SOLVENT ADDITIVES
  • SELF-ORGANIZATION
  • DEVICE EFFICIENCY
  • SMALL MOLECULES
  • ACTIVE LAYERS
  • SIDE-CHAINS

Fingerprint

Dive into the research topics of 'Comparison of additive amount used in spin-coated and roll-coated organic solar cells'. Together they form a unique fingerprint.

Cite this