Comparative study of PBI Cross Linked Utilizing Agents of Varying Steric Configurations

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Abstract

The high thermal and chemical stability of poly[2,2'-(m-phenylene)-5,5' bibenzimidazole] (PBI) accounts for its wise spread use in high temperature polymer electrolyte membrane fuel cells (HT- PEMFC). By doping the membrane with phosphoric acid (PA) ionic conductivity is obtained. Thus conductivity is dependent on the amount of PA present within the membrane. However mechanical properties are reduced are significantly reduced due to the plasticizing effect shown by PA [1]. This effect is due to PBI chain displacement. This effect can be lessened by use of cross linking [2-4]. This can be obtained using ionic or covalent cross linking. When considering such, little attention is devoted to explore the effect of the sterical configuration of the cross linking agent.
In this contribution three different cross linking agents are utilized to evaluate how these affects final membrane properties.
Original languageEnglish
Title of host publicationISPE-XV, Uppsala 15-19th August 2016
Publication date2016
Pages124-124
Article numberP49
Publication statusPublished - 2016
Event15th International Symposium on Polymer Electrolytes - Uppsala, Sweden
Duration: 15 Aug 201619 Aug 2016
Conference number: 15
https://www.delegia.com/ispe2016

Conference

Conference15th International Symposium on Polymer Electrolytes
Number15
CountrySweden
CityUppsala
Period15/08/201619/08/2016
Internet address

Cite this

Kirkebcek, A., Aili, D., Li, Q., & Jensen, J. O. (2016). Comparative study of PBI Cross Linked Utilizing Agents of Varying Steric Configurations. In ISPE-XV, Uppsala 15-19th August 2016 (pp. 124-124). [P49]
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abstract = "The high thermal and chemical stability of poly[2,2'-(m-phenylene)-5,5' bibenzimidazole] (PBI) accounts for its wise spread use in high temperature polymer electrolyte membrane fuel cells (HT- PEMFC). By doping the membrane with phosphoric acid (PA) ionic conductivity is obtained. Thus conductivity is dependent on the amount of PA present within the membrane. However mechanical properties are reduced are significantly reduced due to the plasticizing effect shown by PA [1]. This effect is due to PBI chain displacement. This effect can be lessened by use of cross linking [2-4]. This can be obtained using ionic or covalent cross linking. When considering such, little attention is devoted to explore the effect of the sterical configuration of the cross linking agent.In this contribution three different cross linking agents are utilized to evaluate how these affects final membrane properties.",
author = "Andreas Kirkebcek and David Aili and Qingfeng Li and Jensen, {Jens Oluf}",
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Kirkebcek, A, Aili, D, Li, Q & Jensen, JO 2016, Comparative study of PBI Cross Linked Utilizing Agents of Varying Steric Configurations. in ISPE-XV, Uppsala 15-19th August 2016., P49, pp. 124-124, 15th International Symposium on Polymer Electrolytes, Uppsala, Sweden, 15/08/2016.

Comparative study of PBI Cross Linked Utilizing Agents of Varying Steric Configurations. / Kirkebcek, Andreas; Aili, David; Li, Qingfeng; Jensen, Jens Oluf.

ISPE-XV, Uppsala 15-19th August 2016. 2016. p. 124-124 P49.

Research output: Chapter in Book/Report/Conference proceedingConference abstract in proceedingsResearchpeer-review

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AU - Li, Qingfeng

AU - Jensen, Jens Oluf

PY - 2016

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N2 - The high thermal and chemical stability of poly[2,2'-(m-phenylene)-5,5' bibenzimidazole] (PBI) accounts for its wise spread use in high temperature polymer electrolyte membrane fuel cells (HT- PEMFC). By doping the membrane with phosphoric acid (PA) ionic conductivity is obtained. Thus conductivity is dependent on the amount of PA present within the membrane. However mechanical properties are reduced are significantly reduced due to the plasticizing effect shown by PA [1]. This effect is due to PBI chain displacement. This effect can be lessened by use of cross linking [2-4]. This can be obtained using ionic or covalent cross linking. When considering such, little attention is devoted to explore the effect of the sterical configuration of the cross linking agent.In this contribution three different cross linking agents are utilized to evaluate how these affects final membrane properties.

AB - The high thermal and chemical stability of poly[2,2'-(m-phenylene)-5,5' bibenzimidazole] (PBI) accounts for its wise spread use in high temperature polymer electrolyte membrane fuel cells (HT- PEMFC). By doping the membrane with phosphoric acid (PA) ionic conductivity is obtained. Thus conductivity is dependent on the amount of PA present within the membrane. However mechanical properties are reduced are significantly reduced due to the plasticizing effect shown by PA [1]. This effect is due to PBI chain displacement. This effect can be lessened by use of cross linking [2-4]. This can be obtained using ionic or covalent cross linking. When considering such, little attention is devoted to explore the effect of the sterical configuration of the cross linking agent.In this contribution three different cross linking agents are utilized to evaluate how these affects final membrane properties.

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BT - ISPE-XV, Uppsala 15-19th August 2016

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Kirkebcek A, Aili D, Li Q, Jensen JO. Comparative study of PBI Cross Linked Utilizing Agents of Varying Steric Configurations. In ISPE-XV, Uppsala 15-19th August 2016. 2016. p. 124-124. P49