Chemically extracted nanocellulose from sisal fibres by a simple and industrially relevant process

Jon Trifol Guzman, Cecile Sillard, D. Plackett, Peter Szabo, Julien Bras, Anders Egede Daugaard

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Abstract

A novel type of acetylated cellulose nanofibre (CNF) was extracted successfully from sisal fibres using chemical methods. Initially, a strong alkali treatment was used to swell the fibres, followed by a bleaching step to remove the residual lignin and finally an acetylation step to reduce the impact of the intermolecular hydrogen bonds in the nanocellulose. The result of this sequence of up-scalable chemical treatments was a pulp consisting mainly of micro-sized fibres, which allowed simpler handling through filtration and purification steps and permitted the isolation of an intermediate product with a high solids content. An aqueous dispersion of CNF could be obtained directly from this intermediate pulp by simple magnetic stirring. As a proof of concept, the dispersion was used directly for preparing a highly translucent CNF film, illustrating that there are no large aggregates in the prepared CNF dispersion. Finally, CNF films with alkali extracts were also prepared, resulting in flatter films with an increased mass yield and improved mechanical strength.
Original languageEnglish
JournalCellulose
Volume24
Issue number1
Pages (from-to)107–118
ISSN0969-0239
DOIs
Publication statusPublished - 2017

Keywords

  • Sisal fibres
  • Cellulose nanofibres (CNFs)
  • Cellulose films
  • Acetylation
  • Nanofibers

Cite this

Trifol Guzman, Jon ; Sillard, Cecile ; Plackett, D. ; Szabo, Peter ; Bras, Julien ; Daugaard, Anders Egede. / Chemically extracted nanocellulose from sisal fibres by a simple and industrially relevant process. In: Cellulose. 2017 ; Vol. 24, No. 1. pp. 107–118.
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abstract = "A novel type of acetylated cellulose nanofibre (CNF) was extracted successfully from sisal fibres using chemical methods. Initially, a strong alkali treatment was used to swell the fibres, followed by a bleaching step to remove the residual lignin and finally an acetylation step to reduce the impact of the intermolecular hydrogen bonds in the nanocellulose. The result of this sequence of up-scalable chemical treatments was a pulp consisting mainly of micro-sized fibres, which allowed simpler handling through filtration and purification steps and permitted the isolation of an intermediate product with a high solids content. An aqueous dispersion of CNF could be obtained directly from this intermediate pulp by simple magnetic stirring. As a proof of concept, the dispersion was used directly for preparing a highly translucent CNF film, illustrating that there are no large aggregates in the prepared CNF dispersion. Finally, CNF films with alkali extracts were also prepared, resulting in flatter films with an increased mass yield and improved mechanical strength.",
keywords = "Sisal fibres, Cellulose nanofibres (CNFs), Cellulose films, Acetylation, Nanofibers",
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Chemically extracted nanocellulose from sisal fibres by a simple and industrially relevant process. / Trifol Guzman, Jon; Sillard, Cecile; Plackett, D.; Szabo, Peter; Bras, Julien; Daugaard, Anders Egede.

In: Cellulose, Vol. 24, No. 1, 2017, p. 107–118.

Research output: Contribution to journalJournal articleResearchpeer-review

TY - JOUR

T1 - Chemically extracted nanocellulose from sisal fibres by a simple and industrially relevant process

AU - Trifol Guzman, Jon

AU - Sillard, Cecile

AU - Plackett, D.

AU - Szabo, Peter

AU - Bras, Julien

AU - Daugaard, Anders Egede

PY - 2017

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N2 - A novel type of acetylated cellulose nanofibre (CNF) was extracted successfully from sisal fibres using chemical methods. Initially, a strong alkali treatment was used to swell the fibres, followed by a bleaching step to remove the residual lignin and finally an acetylation step to reduce the impact of the intermolecular hydrogen bonds in the nanocellulose. The result of this sequence of up-scalable chemical treatments was a pulp consisting mainly of micro-sized fibres, which allowed simpler handling through filtration and purification steps and permitted the isolation of an intermediate product with a high solids content. An aqueous dispersion of CNF could be obtained directly from this intermediate pulp by simple magnetic stirring. As a proof of concept, the dispersion was used directly for preparing a highly translucent CNF film, illustrating that there are no large aggregates in the prepared CNF dispersion. Finally, CNF films with alkali extracts were also prepared, resulting in flatter films with an increased mass yield and improved mechanical strength.

AB - A novel type of acetylated cellulose nanofibre (CNF) was extracted successfully from sisal fibres using chemical methods. Initially, a strong alkali treatment was used to swell the fibres, followed by a bleaching step to remove the residual lignin and finally an acetylation step to reduce the impact of the intermolecular hydrogen bonds in the nanocellulose. The result of this sequence of up-scalable chemical treatments was a pulp consisting mainly of micro-sized fibres, which allowed simpler handling through filtration and purification steps and permitted the isolation of an intermediate product with a high solids content. An aqueous dispersion of CNF could be obtained directly from this intermediate pulp by simple magnetic stirring. As a proof of concept, the dispersion was used directly for preparing a highly translucent CNF film, illustrating that there are no large aggregates in the prepared CNF dispersion. Finally, CNF films with alkali extracts were also prepared, resulting in flatter films with an increased mass yield and improved mechanical strength.

KW - Sisal fibres

KW - Cellulose nanofibres (CNFs)

KW - Cellulose films

KW - Acetylation

KW - Nanofibers

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