Characterization and parametrical study of Rh-TPPTS supported ionic liquid phase (SILP) catalysts for ethylene hydroformylation

Nguyen Thi Ha Hanh; Duc Truong Duc; Vu Dao Thang; Thang Le Minh; Anders Riisager; Rasmus Fehrmann

doi:10.1016/j.catcom.2012.01.018

Characterization and parametrical study of Rh-TPPTS supported ionic liquid phase (SILP) catalysts for ethylene hydroformylation

Nguyen Thi Ha Hanh, Duc Truong Duc, Vu Dao Thang, Thang Le Minh, Anders Riisager, Rasmus Fehrmann

Department of Chemistry

Hanoi University of Science and Technology

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

The supported ionic liquid phase (SILP) catalysis technology was applied to continuous, gas-phase hydroformylation of ethylene. Rh-TPPTS SILP catalysts with relatively low ionic liquid loading were shown to be stable and highly activity for ethylene hydroformylation. However, the catalytic activity, BET surface area and pore morphology of the catalysts depended on the content of ionic liquid. Hence, catalysts with high ionic liquid loading content showed deactivation at high reaction temperatures, possibly caused by redistribution of ionic liquid out of the pores under these conditions. (C) 2012 Elsevier B.V. All rights reserved.

Original language	English
Journal	Catalysis Communications
Volume	25
Pages (from-to)	136-141
ISSN	1566-7367
DOIs	https://doi.org/10.1016/j.catcom.2012.01.018
Publication status	Published - 2012

Keywords

Supported ionic liquid phase
Ionic liquid
Hydroformylation
Ethylene
Silica

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title = "Characterization and parametrical study of Rh-TPPTS supported ionic liquid phase (SILP) catalysts for ethylene hydroformylation",

abstract = "The supported ionic liquid phase (SILP) catalysis technology was applied to continuous, gas-phase hydroformylation of ethylene. Rh-TPPTS SILP catalysts with relatively low ionic liquid loading were shown to be stable and highly activity for ethylene hydroformylation. However, the catalytic activity, BET surface area and pore morphology of the catalysts depended on the content of ionic liquid. Hence, catalysts with high ionic liquid loading content showed deactivation at high reaction temperatures, possibly caused by redistribution of ionic liquid out of the pores under these conditions. (C) 2012 Elsevier B.V. All rights reserved.",

keywords = "Supported ionic liquid phase, Ionic liquid, Hydroformylation, Ethylene, Silica",

author = "Hanh, {Nguyen Thi Ha} and Duc, {Duc Truong} and Thang, {Vu Dao} and Minh, {Thang Le} and Anders Riisager and Rasmus Fehrmann",

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T1 - Characterization and parametrical study of Rh-TPPTS supported ionic liquid phase (SILP) catalysts for ethylene hydroformylation

AU - Hanh, Nguyen Thi Ha

AU - Duc, Duc Truong

AU - Thang, Vu Dao

AU - Minh, Thang Le

AU - Riisager, Anders

AU - Fehrmann, Rasmus

PY - 2012

Y1 - 2012

N2 - The supported ionic liquid phase (SILP) catalysis technology was applied to continuous, gas-phase hydroformylation of ethylene. Rh-TPPTS SILP catalysts with relatively low ionic liquid loading were shown to be stable and highly activity for ethylene hydroformylation. However, the catalytic activity, BET surface area and pore morphology of the catalysts depended on the content of ionic liquid. Hence, catalysts with high ionic liquid loading content showed deactivation at high reaction temperatures, possibly caused by redistribution of ionic liquid out of the pores under these conditions. (C) 2012 Elsevier B.V. All rights reserved.

AB - The supported ionic liquid phase (SILP) catalysis technology was applied to continuous, gas-phase hydroformylation of ethylene. Rh-TPPTS SILP catalysts with relatively low ionic liquid loading were shown to be stable and highly activity for ethylene hydroformylation. However, the catalytic activity, BET surface area and pore morphology of the catalysts depended on the content of ionic liquid. Hence, catalysts with high ionic liquid loading content showed deactivation at high reaction temperatures, possibly caused by redistribution of ionic liquid out of the pores under these conditions. (C) 2012 Elsevier B.V. All rights reserved.

KW - Supported ionic liquid phase

KW - Ionic liquid

KW - Hydroformylation

KW - Ethylene

KW - Silica

U2 - 10.1016/j.catcom.2012.01.018

DO - 10.1016/j.catcom.2012.01.018

M3 - Journal article

SN - 1566-7367

VL - 25

SP - 136

EP - 141

JO - Catalysis Communications

JF - Catalysis Communications

ER -

Characterization and parametrical study of Rh-TPPTS supported ionic liquid phase (SILP) catalysts for ethylene hydroformylation

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Keywords

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