Characteristics of Sulfuric Acid Condensation on Cylinder Liners of Large Two-Stroke Marine Engines

Rasmus Lage Cordtz, Stefan Mayer, Jesper Schramm, Svend S. Eskildsen

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The present work seeks to clarify the characteristics of sulfuric acid condensation on the cylinder liner of a large two–stroke marine engine. The liner is directly exposed to the cylin-der gas (i.e. no protective lube oil film) and is represented by a constant temperature over the full stroke. Formation of corrosive sulfuric acid in the cylinder gas is modeled with a cali-brated engine model that incorporates a detailed sulfur reaction mechanism. Condensation of sulfuric acid follows the analogy between heat and mass transfer. Average bulk gas acid dew points are calculated by applying two-phase thermochemistry of the binary H2O-H2SO4 system. Max dew points of typically more than 200 °C are modeled close to max pressure and variations in terms of operating conditions are not large. However small increments of the dew point provided by e.g. the residual gas fraction, operating pressure, sulfur content and charge air humidity acts to increase the surface area that is exposed to condensation. Depending on the actual liner temperature the deposition of sulfuric acid can be very sensi-tive to the operating strategy. A higher liner temperature theoretically provides the means to hamper sulfuric acid condensation.
Original languageEnglish
Publication date2014
Number of pages14
Publication statusPublished - 2014
Event 3. Rostocker Großmotorentagung - Universität Rostock, Rostock, Germany
Duration: 18 Sep 201419 Sep 2014
Conference number: 3


Conference 3. Rostocker Großmotorentagung
LocationUniversität Rostock

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