TY - JOUR
T1 - catena-Poly[tetrasodium [[cis-dioxidotrans-bis(sulfato-kappaO)molybdate(VI)]-my-sulfato-kappaO:O']]
AU - Schäffer, Susan Jeanne Cline
AU - Berg, Rolf W.
PY - 2008
Y1 - 2008
N2 - Single crystals of the title compound, {Na4[MoVIO2(SO4)3]}n, were grown from a melt of MoO3 and Na2SO4 in Na2S2O7. In
contrast to the structure of the isoformular K compound,
K4[MoVIO2(SO4)3], with its monomeric anion, this sodium
analogue contains a polymeric anion of the type
{[MoVIO2(SO4)2--(SO4)]4}n. The MoVI cations, surrounded
by two tightly bonded O atoms and four O atoms of one
bridging and two terminal sulfato ligands, form zigzag chains parallel to [100]. All four Na+ cations are situated between the anionic chains and have distorted octahedral coordination spheres.
AB - Single crystals of the title compound, {Na4[MoVIO2(SO4)3]}n, were grown from a melt of MoO3 and Na2SO4 in Na2S2O7. In
contrast to the structure of the isoformular K compound,
K4[MoVIO2(SO4)3], with its monomeric anion, this sodium
analogue contains a polymeric anion of the type
{[MoVIO2(SO4)2--(SO4)]4}n. The MoVI cations, surrounded
by two tightly bonded O atoms and four O atoms of one
bridging and two terminal sulfato ligands, form zigzag chains parallel to [100]. All four Na+ cations are situated between the anionic chains and have distorted octahedral coordination spheres.
U2 - 10.1107/S1600536808030328
DO - 10.1107/S1600536808030328
M3 - Journal article
C2 - 21580809
VL - e64
SP - i73
JO - Acta Crystallographica. Section E: Structure Reports Online
JF - Acta Crystallographica. Section E: Structure Reports Online
SN - 1600-5368
ER -