Catalytic reduction of NO by methane using a Pt/C/polybenzimidazole/Pt/C fuel cell

Irina Petrushina, Lars Nilausen Cleemann, Rasmus Refshauge, Niels Bjerrum, Viktor Bandur

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Abstract

The catalytic NO reduction by methane was studied using a (NO,CH4,Ar),Pt|polybenzimidazole(PBI)–H3PO4|Pt,(H2,Ar) fuel cell at 135 and 165°C. It has been found that, without any reducing agent (like CH4), NO can be electrochemically reduced in the (NO, Ar), Pt/C|PBI–H3PO4|Pt/C, (H2,Ar) fuel cell with participation of H+ or electrochemically produced hydrogen. When added, methane partially suppresses the electrochemical reduction of NO. Methane outlet concentration monitoring has shown the CH4 participation in the chemical catalytic reduction, i.e., methane co-adsorption with NO inhibited the electrochemical NO reduction and introduced a dominant chemical path of the NO reduction. The products of the NO reduction with methane were N2, C2H4, and water. The catalytic NO reduction by methane was promoted when the catalyst was negatively polarized (−0.2 V). Repeated negative polarization of the catalyst increased the NO conversion. Maximum NO conversion was 48%. This effect was explained as a result of the reaction of the electrochemically produced hydrogen.
Original languageEnglish
JournalJournal of The Electrochemical Society
Volume154
Issue number6
Pages (from-to)E84-E90
ISSN0013-4651
DOIs
Publication statusPublished - 2007

Bibliographical note

Copyright The Electrochemical Society, Inc. [2007]. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS).

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