Catalytic reduction of nitrogen to produce ammonia by bismuth-based catalysts: State of the art and future prospects

Qiang Hao, Chuangwei Liu, Guohua Jia, Yuan Wang, Hamidreza Arandiyan, Wei Wei, Bing Jie Ni*

*Corresponding author for this work

Research output: Contribution to journalReviewResearchpeer-review

Abstract

Ammonia is a key industrial raw material for fertilisers, chemicals and energy. The annual artificial ammonia synthesis via the Haber-Bosch process results in about 2% of global energy consumption and can lead to 1.6% CO2 emission. Hence, it is urgent to develop low-cost and environmentally friendly approaches for artificial ammonia synthesis under ambient conditions. Recently, bismuth (Bi)-based catalysts have attracted great interest due to their excellent nitrogen fixation performance in electrochemical and photocatalytic fields. However, there is still a lack of a comprehensive review on Bi-based nitrogen-fixation materials focusing on their crystal structure, surface engineering and modification methods, which is highly desirable for facilitating their further development towards applications. Herein, we provide an up-to-date review on Bi-based nitrogen-fixation materials and classify them as metallic Bi, bismuth oxide, bismuth oxyhalide, and Bi-based polyoxometalates. Starting from the underlying crystal structure, we analyse the internal electric field, surface engineering and modification methods of Bi-based nitrogen fixation materials. Then, we highlight the latest achievements of Bi-based materials and reveal the challenges and obstacles in the development and application of Bi-based nitrogen-fixation materials. More importantly, this review presents the surface and structure engineering strategies, and future directions for the development of new Bi-based nitrogen-fixation materials under ambient conditions.

Original languageEnglish
JournalMaterials Horizons
Volume7
Issue number4
Pages (from-to)1014-1029
ISSN2051-6347
DOIs
Publication statusPublished - 2020

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