Carbene Reactions: Part 16. Thermolyses of Norbornadiene-7-spiro-2-(1,3-dithiolana)-S-Oxides

R. W. Hoffmann; W. Barth; Lars Carlsen; Helge Egsgaard

doi:10.1039/P29830001687

Carbene Reactions: Part 16. Thermolyses of Norbornadiene-7-spiro-2-(1,3-dithiolana)-S-Oxides

R. W. Hoffmann, W. Barth, Lars Carlsen, Helge Egsgaard

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

The gas-phase thermolysis of the norbornadienespirodithiolane S-oxides (5) and (7) led to benzene, ethylene, and carbon disulphide as the major products, possibly involving carbon disulphide oxides as intermediates. Thermolyses of the related sulphones (9) or (14) led to completely different product patterns.

Original language	English
Journal	Royal Chemical Society. Journal. Perkin Transactions 2
Issue number	9
Pages (from-to)	1687-1692
ISSN	1472-779X
DOIs	https://doi.org/10.1039/P29830001687
Publication status	Published - 1983

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title = "Carbene Reactions: Part 16. Thermolyses of Norbornadiene-7-spiro-2-(1,3-dithiolana)-S-Oxides",

abstract = "The gas-phase thermolysis of the norbornadienespirodithiolane S-oxides (5) and (7) led to benzene, ethylene, and carbon disulphide as the major products, possibly involving carbon disulphide oxides as intermediates. Thermolyses of the related sulphones (9) or (14) led to completely different product patterns.",

author = "Hoffmann, {R. W.} and W. Barth and Lars Carlsen and Helge Egsgaard",

year = "1983",

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AU - Hoffmann, R. W.

AU - Barth, W.

AU - Carlsen, Lars

AU - Egsgaard, Helge

PY - 1983

Y1 - 1983

N2 - The gas-phase thermolysis of the norbornadienespirodithiolane S-oxides (5) and (7) led to benzene, ethylene, and carbon disulphide as the major products, possibly involving carbon disulphide oxides as intermediates. Thermolyses of the related sulphones (9) or (14) led to completely different product patterns.

AB - The gas-phase thermolysis of the norbornadienespirodithiolane S-oxides (5) and (7) led to benzene, ethylene, and carbon disulphide as the major products, possibly involving carbon disulphide oxides as intermediates. Thermolyses of the related sulphones (9) or (14) led to completely different product patterns.

U2 - 10.1039/P29830001687

DO - 10.1039/P29830001687

M3 - Journal article

SN - 1472-779X

SP - 1687

EP - 1692

JO - Royal Chemical Society. Journal. Perkin Transactions 2

JF - Royal Chemical Society. Journal. Perkin Transactions 2

IS - 9

ER -

Carbene Reactions: Part 16. Thermolyses of Norbornadiene-7-spiro-2-(1,3-dithiolana)-S-Oxides

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