Carbene Reactions: Part 16. Thermolyses of Norbornadiene-7-spiro-2-(1,3-dithiolana)-S-Oxides

R. W. Hoffmann, W. Barth, Lars Carlsen, Helge Egsgaard

    Research output: Contribution to journalJournal articlepeer-review

    Abstract

    The gas-phase thermolysis of the norbornadienespirodithiolane S-oxides (5) and (7) led to benzene, ethylene, and carbon disulphide as the major products, possibly involving carbon disulphide oxides as intermediates. Thermolyses of the related sulphones (9) or (14) led to completely different product patterns.
    Original languageEnglish
    JournalRoyal Chemical Society. Journal. Perkin Transactions 2
    Issue number9
    Pages (from-to)1687-1692
    ISSN1472-779X
    DOIs
    Publication statusPublished - 1983

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