Calculation of Interfacial Tensions of Hydrocarbon-water Systems under Reservoir Conditions

You-Xiang Zuo, Erling Halfdan Stenby

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Abstract

Assuming that the number densities of each component in a mixture are linearly distributed across the interface between the coexisting vapor-liquid or liquid-liquid phases, we developed in this research work a linear-gradient-theory (LGT) model for computing the interfacial tension of hydrocarbon-water mixtures on the basis of the SRK equation of state. With this model, it is unnecessary to solve the time-consuming density-profile equations of the gradient-theory model. In addition, a correlation was developed for representing the effect of electrolytes on the interfacial tension of hydrocarbon-brine systems. The new model was tested on a number of hydrocarbon-water/brine mixtures and two crude oil-water systems under reservoir conditions. The results show good agreement between the predicted and the experimental interfacial tension data.
Original languageEnglish
JournalIn Situ
Volume22
Issue number2
Pages (from-to)157-180
Publication statusPublished - 1998

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