Bulk and surface morphologies of ABC miktoarm star terpolymers comprised of PDMS, PI and PMMA arms

Research output: Contribution to journalJournal article – Annual report year: 2018Researchpeer-review

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Bulk and surface morphologies of ABC miktoarm star terpolymers comprised of PDMS, PI and PMMA arms. / Chernyy, Sergey; Kirkensgaard, Jacob Judas Kain; Mahalik, Jyoti P. ; Kim, Hyeyoung ; Arras, Matthias M. L. ; Kumar, Rajeev ; Sumpter, Bobby G. ; Smith, Gregory S. ; Mortensen, Kell; Russell, Thomas P.; Almdal, Kristoffer.

In: Macromolecules, Vol. 51, No. 3, 2018, p. 1041-1051.

Research output: Contribution to journalJournal article – Annual report year: 2018Researchpeer-review

Harvard

Chernyy, S, Kirkensgaard, JJK, Mahalik, JP, Kim, H, Arras, MML, Kumar, R, Sumpter, BG, Smith, GS, Mortensen, K, Russell, TP & Almdal, K 2018, 'Bulk and surface morphologies of ABC miktoarm star terpolymers comprised of PDMS, PI and PMMA arms', Macromolecules, vol. 51, no. 3, pp. 1041-1051. https://doi.org/10.1021/acs.macromol.7b02485

APA

CBE

Chernyy S, Kirkensgaard JJK, Mahalik JP, Kim H, Arras MML, Kumar R, Sumpter BG, Smith GS, Mortensen K, Russell TP, Almdal K. 2018. Bulk and surface morphologies of ABC miktoarm star terpolymers comprised of PDMS, PI and PMMA arms. Macromolecules. 51(3):1041-1051. https://doi.org/10.1021/acs.macromol.7b02485

MLA

Vancouver

Author

Chernyy, Sergey ; Kirkensgaard, Jacob Judas Kain ; Mahalik, Jyoti P. ; Kim, Hyeyoung ; Arras, Matthias M. L. ; Kumar, Rajeev ; Sumpter, Bobby G. ; Smith, Gregory S. ; Mortensen, Kell ; Russell, Thomas P. ; Almdal, Kristoffer. / Bulk and surface morphologies of ABC miktoarm star terpolymers comprised of PDMS, PI and PMMA arms. In: Macromolecules. 2018 ; Vol. 51, No. 3. pp. 1041-1051.

Bibtex

@article{7ca560cccd0e456491e9bc0eb34c8e9f,
title = "Bulk and surface morphologies of ABC miktoarm star terpolymers comprised of PDMS, PI and PMMA arms",
abstract = "DIM miktoarm star copolymers, composed of polydimethylsiloxane [D], poly(1,4-isoprene) [I], and poly(methyl methacrylate) [M], were synthesized using a newly developed linking methodology with 4-allyl-1,1-diphenylethylene as a linking agent. The equilibrium bulk morphologies of the DIM stars were found to range from [6.6.6] tiling patterns to alternating lamellar and alternating cylindrical morphologies, as determined experimentally by small-angle X-ray scattering and transmission electron microscopy and confirmed by dissipative particle dynamics and self-consistent field theory based arguments. The thin film morphologies, which differ from those found in the bulk, were identified by scanning electron microscopy, coupled with oxygen plasma etching. Square arrays of the PDMS nanodots and empty core cylinders were formed on silica after oxygen plasma removal of the poly(1,4-isoprene) and poly(methyl methacrylate) which generated nanostructured substrates decorated with these features readily observable.",
author = "Sergey Chernyy and Kirkensgaard, {Jacob Judas Kain} and Mahalik, {Jyoti P.} and Hyeyoung Kim and Arras, {Matthias M. L.} and Rajeev Kumar and Sumpter, {Bobby G.} and Smith, {Gregory S.} and Kell Mortensen and Russell, {Thomas P.} and Kristoffer Almdal",
year = "2018",
doi = "10.1021/acs.macromol.7b02485",
language = "English",
volume = "51",
pages = "1041--1051",
journal = "Macromolecules",
issn = "0024-9297",
publisher = "American Chemical Society",
number = "3",

}

RIS

TY - JOUR

T1 - Bulk and surface morphologies of ABC miktoarm star terpolymers comprised of PDMS, PI and PMMA arms

AU - Chernyy, Sergey

AU - Kirkensgaard, Jacob Judas Kain

AU - Mahalik, Jyoti P.

AU - Kim, Hyeyoung

AU - Arras, Matthias M. L.

AU - Kumar, Rajeev

AU - Sumpter, Bobby G.

AU - Smith, Gregory S.

AU - Mortensen, Kell

AU - Russell, Thomas P.

AU - Almdal, Kristoffer

PY - 2018

Y1 - 2018

N2 - DIM miktoarm star copolymers, composed of polydimethylsiloxane [D], poly(1,4-isoprene) [I], and poly(methyl methacrylate) [M], were synthesized using a newly developed linking methodology with 4-allyl-1,1-diphenylethylene as a linking agent. The equilibrium bulk morphologies of the DIM stars were found to range from [6.6.6] tiling patterns to alternating lamellar and alternating cylindrical morphologies, as determined experimentally by small-angle X-ray scattering and transmission electron microscopy and confirmed by dissipative particle dynamics and self-consistent field theory based arguments. The thin film morphologies, which differ from those found in the bulk, were identified by scanning electron microscopy, coupled with oxygen plasma etching. Square arrays of the PDMS nanodots and empty core cylinders were formed on silica after oxygen plasma removal of the poly(1,4-isoprene) and poly(methyl methacrylate) which generated nanostructured substrates decorated with these features readily observable.

AB - DIM miktoarm star copolymers, composed of polydimethylsiloxane [D], poly(1,4-isoprene) [I], and poly(methyl methacrylate) [M], were synthesized using a newly developed linking methodology with 4-allyl-1,1-diphenylethylene as a linking agent. The equilibrium bulk morphologies of the DIM stars were found to range from [6.6.6] tiling patterns to alternating lamellar and alternating cylindrical morphologies, as determined experimentally by small-angle X-ray scattering and transmission electron microscopy and confirmed by dissipative particle dynamics and self-consistent field theory based arguments. The thin film morphologies, which differ from those found in the bulk, were identified by scanning electron microscopy, coupled with oxygen plasma etching. Square arrays of the PDMS nanodots and empty core cylinders were formed on silica after oxygen plasma removal of the poly(1,4-isoprene) and poly(methyl methacrylate) which generated nanostructured substrates decorated with these features readily observable.

U2 - 10.1021/acs.macromol.7b02485

DO - 10.1021/acs.macromol.7b02485

M3 - Journal article

VL - 51

SP - 1041

EP - 1051

JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 3

ER -