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Bandlike transport in pentacene and functionalized pentacene thin films revealed by subpicosecond transient photoconductivity measurements

  • O. Ostroverkhova
  • , David Cooke
  • , S. Shcherbyna
  • , R. F. Egerton
  • , F. A. Hegmann
  • , R. R. Tykwinski
  • , J. E. Anthony
  • University of Alberta
  • University of Kentucky

Research output: Contribution to journal › Journal article › Research

Abstract

We observe bandlike transport in pentacene and functionalized pentacene thin films using time-resolved terahertz pulse spectroscopy. The measured transient photoconductivity exhibits fast (<400 fs) photogeneration of mobile charge carriers and reveals a transient carrier mobility that increases as the temperature decreases from 300 K down to 10 K, indicative of bandlike transport over subpicosecond time scales. A wavelength-independent photoconductive signal is observed. The transient photoconductivity in the thin-film samples exhibits a single-exponential decay, whereas a power-law decay is seen in single-crystal samples.
Original languageEnglish
JournalPhysical Review B-Condensed Matter
Volume71
Issue number3
Pages (from-to)035204
ISSN0163-1829
DOIs
Publication statusPublished - 2005
Externally publishedYes

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