TY - JOUR
T1 - Atmospheric chemistry of trans-CF3CH{double bond, long}CHF: Kinetics of the gas-phase reactions with Cl atoms, OH radicals, and O3
AU - Søndergaard, Roar
AU - Nielsen, Ole John
AU - Hurley, M.D.
AU - Wallington, T.J.
AU - Singh, R.
PY - 2007
Y1 - 2007
N2 - Long path length FTIR-smog chamber techniques were used to measure k(Cl + t-CF3CH{double bond, long}CHF) = (4.64 ± 0.59) × 10-11, k(OH + t-CF3CH{double bond, long}CHF) = (9.25 ± 1.72) × 10-13, and k(O3 + t-CF3CH{double bond, long}CHF) = (2.81 ± 0.21) × 10-21 cm3 molecule-1 s-1 in 700 Torr of air diluent at 296 K. The atmospheric lifetime of t-CF3CH{double bond, long}CHF is determined by its reaction with OH and is approximately two weeks. t-CF3CH{double bond, long}CHF has an integrated IR absorption cross section(650-2000 cm-1) of (1.94 ± 0.10) × 10-16 cm molecule-1 and a global warming potential of approximately 6 (100-year time horizon). As part of this work the reaction of ozone with C2H4 was determined to proceed with a rate constant of (1.46 ± 0.13) × 10-18 cm3 molecule-1 s-1 in 700 Torr of air at 296 K. © 2007.
AB - Long path length FTIR-smog chamber techniques were used to measure k(Cl + t-CF3CH{double bond, long}CHF) = (4.64 ± 0.59) × 10-11, k(OH + t-CF3CH{double bond, long}CHF) = (9.25 ± 1.72) × 10-13, and k(O3 + t-CF3CH{double bond, long}CHF) = (2.81 ± 0.21) × 10-21 cm3 molecule-1 s-1 in 700 Torr of air diluent at 296 K. The atmospheric lifetime of t-CF3CH{double bond, long}CHF is determined by its reaction with OH and is approximately two weeks. t-CF3CH{double bond, long}CHF has an integrated IR absorption cross section(650-2000 cm-1) of (1.94 ± 0.10) × 10-16 cm molecule-1 and a global warming potential of approximately 6 (100-year time horizon). As part of this work the reaction of ozone with C2H4 was determined to proceed with a rate constant of (1.46 ± 0.13) × 10-18 cm3 molecule-1 s-1 in 700 Torr of air at 296 K. © 2007.
U2 - 10.1016/j.cplett.2007.06.084
DO - 10.1016/j.cplett.2007.06.084
M3 - Journal article
SN - 0009-2614
VL - 443
SP - 199
EP - 204
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 4-6
ER -