Abstract
Asymmetric Homer-Wadsworth-Emmons reactions between chiral phosphonate reagents and various meso-dialdehydes have been investigated. A mechanistic model useful for rationalizing the experimentally observed stereoselectivities is presented. Furthermore; strategies for applying these reactions to the stereocontrolled preparation of chiral heterocyclic building blocks have been developed.
Original language | English |
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Journal | Phosphorus, Sulfur and Silicon and the Related Elements |
Volume | 144-146 |
Pages (from-to) | 169-172 |
ISSN | 1042-6507 |
Publication status | Published - 1999 |
Event | XIV International Conference on Phosphorus Chemistry - Cincinnati,OH, United States Duration: 12 Jul 1998 → 17 Jul 1998 Conference number: 14 |
Conference
Conference | XIV International Conference on Phosphorus Chemistry |
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Number | 14 |
Country/Territory | United States |
City | Cincinnati,OH |
Period | 12/07/1998 → 17/07/1998 |