Application of HPLC capacity coefficients to characterize the sorption of polycyclic aromatic compounds to humic acid

T. Nielsen; C. Helweg; K. Siigur; U. Kirso

doi:10.1016/S0039-9140(97)00083-0

Application of HPLC capacity coefficients to characterize the sorption of polycyclic aromatic compounds to humic acid

T. Nielsen
, C. Helweg
, K. Siigur
, U. Kirso

Research output: Contribution to journal › Journal article › Research

Abstract

The sorption coefficients to humic acid of 46 PAC having a wide range in polarity were compared with the capacity coefficients of the PAC to a non-polar HPLC column material (ODS) and a polar one (Diol). It is shown that polar interactions contribute to the sorption of polar PAC in addition to the non-polar interactions. The results also suggest that humic acid may contain different hydrophilic adsorption sites. The non-polar column material was only the best model substrate, if the test materials were limited to the hydrophobic unsubstituted PAC, PAH + O,S-PAC. (C) 1997 Elsevier Science B.V.

Original language	English
Journal	Talanta
Volume	44
Issue number	10
Pages (from-to)	1873-1881
ISSN	0039-9140
DOIs	https://doi.org/10.1016/S0039-9140(97)00083-0
Publication status	Published - 1997

Access to Document

10.1016/S0039-9140(97)00083-0

OpenUrl availability

Full text

Cite this

@article{85f1c552a9dc4cb6943d18f4a59b0431,

title = "Application of HPLC capacity coefficients to characterize the sorption of polycyclic aromatic compounds to humic acid",

abstract = "The sorption coefficients to humic acid of 46 PAC having a wide range in polarity were compared with the capacity coefficients of the PAC to a non-polar HPLC column material (ODS) and a polar one (Diol). It is shown that polar interactions contribute to the sorption of polar PAC in addition to the non-polar interactions. The results also suggest that humic acid may contain different hydrophilic adsorption sites. The non-polar column material was only the best model substrate, if the test materials were limited to the hydrophobic unsubstituted PAC, PAH + O,S-PAC. (C) 1997 Elsevier Science B.V. ",

keywords = "Vindenergi og atmosf{\ae}riske processer",

author = "T. Nielsen and C. Helweg and K. Siigur and U. Kirso",

year = "1997",

doi = "10.1016/S0039-9140(97)00083-0",

language = "English",

volume = "44",

pages = "1873--1881",

journal = "Talanta",

issn = "0039-9140",

publisher = "Elsevier",

number = "10",

}

TY - JOUR

T1 - Application of HPLC capacity coefficients to characterize the sorption of polycyclic aromatic compounds to humic acid

AU - Nielsen, T.

AU - Helweg, C.

AU - Siigur, K.

AU - Kirso, U.

PY - 1997

Y1 - 1997

N2 - The sorption coefficients to humic acid of 46 PAC having a wide range in polarity were compared with the capacity coefficients of the PAC to a non-polar HPLC column material (ODS) and a polar one (Diol). It is shown that polar interactions contribute to the sorption of polar PAC in addition to the non-polar interactions. The results also suggest that humic acid may contain different hydrophilic adsorption sites. The non-polar column material was only the best model substrate, if the test materials were limited to the hydrophobic unsubstituted PAC, PAH + O,S-PAC. (C) 1997 Elsevier Science B.V.

AB - The sorption coefficients to humic acid of 46 PAC having a wide range in polarity were compared with the capacity coefficients of the PAC to a non-polar HPLC column material (ODS) and a polar one (Diol). It is shown that polar interactions contribute to the sorption of polar PAC in addition to the non-polar interactions. The results also suggest that humic acid may contain different hydrophilic adsorption sites. The non-polar column material was only the best model substrate, if the test materials were limited to the hydrophobic unsubstituted PAC, PAH + O,S-PAC. (C) 1997 Elsevier Science B.V.

KW - Vindenergi og atmosfæriske processer

U2 - 10.1016/S0039-9140(97)00083-0

DO - 10.1016/S0039-9140(97)00083-0

M3 - Journal article

SN - 0039-9140

VL - 44

SP - 1873

EP - 1881

JO - Talanta

JF - Talanta

IS - 10

ER -

Application of HPLC capacity coefficients to characterize the sorption of polycyclic aromatic compounds to humic acid

Abstract

Access to Document

OpenUrl availability

Fingerprint

Cite this