Galactans are linear structures mainly found in arabinogalactan glycans and RG-I side chains. As a follow-up to our work on both β-(1→3)-linked and β-(1→4)-linked galactans, we herein report a convergent synthesis of β-(1→6)-galactan using our previously synthesized 4,6-benzylidene protected disaccharide as a key building block. However, the regioselective reductive opening of the 4,6-benzylidene protected disaccharide turned out to become more challenging as the length of the oligosaccharide increased and a second differential protected disaccharide building block carrying a chloroacetyl group on the 6-position was used to elongate the chain in a more efficient way.
|Journal||Trends in Carbohydrate Research|
|Publication status||Published - 2017|
- Plant cell wall oligosaccharides