An Ag based brazing system with a tunable thermal expansion for the use as sealant for solid oxide cells

Wolff-Ragnar Kiebach, Kurt Engelbrecht, Laila Grahl-Madsen, Bertil Sieborg, Ming Chen, Johan Hjelm, Kion Norrman, Christodoulos Chatzichristodoulou, Peter Vang Hendriksen

Research output: Contribution to journalJournal articleResearchpeer-review


An Ag-Al2TiO5 composite braze was developed and successfully tested as seal for solid oxide cells. The thermo-mechanical properties of the Ag-Al2TiO5 system and the chemical compatibility between this composite braze and relevant materials used in stacks were characterized and the leak rates as a function of the operation temperature were measured. The thermal expansion coefficient in the Ag-Al2TiO5 system can be tailored by varying the amount of the ceramic filler. The brazing process can be carried out in air, the joining partners showed a good chemical stability and sufficient low leak rates were demonstrated. Furthermore, the long-term stability of the Ag-Al2TiO5 composite braze was studied under relevant SOFC and SOEC conditions. The stability of brazed Crofer/Ag-Al2TiO5/NiO-YSZ assemblies in reducing atmosphere and in pure oxygen was investigated over 500 h at 850 °C. Additionally, a cell component test was performed to investigate the durability of the Ag-Al2TiO5 seal when exposed to dual atmosphere. The seals performed well over 900 h under electrolysis operation conditions (−0.5 A cm2, 850 °C), and no cell degradation related to the Ag-Al2TiO5 sealing was found, indicating that the developed braze system is applicable for the use in SOFC/SOEC stacks.
Original languageEnglish
JournalJournal of Power Sources
Pages (from-to)339-350
Number of pages12
Publication statusPublished - 2016


  • Brazing
  • Sealant
  • Solid oxide fuel cell
  • Solid oxide electrolysis cell
  • Silver
  • Corrosion


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