Alternating and non-alternating Pd-catalysed co- and terpolymerisation of carbon monoxide and alkenes

Eduardo J. Garcia-Suarez, Cyril Godard, Aurora Ruiz, Carmen Claver

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

The co- and terpolymerisation of carbon monoxide and alkenes are usually catalysed by palladium complexes, and the properties of the produced polyketones can be finely tuned by an appropriate choice of catalyst and olefinic monomer. After a general overview of the topic, selected recent advances in this field are described. The use of palladium systems containing modified diphosphane and/or new phosphorus-based ligands, and the results obtained using a series of modular N and S ligands, including chiral ligands, in CO/styrene co- and terpolymerisations are reported. The use of new P-O ligands in non-alternating CO/ethene copolymerisation is also described. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim., Germany, 2007).
Original languageEnglish
JournalEuropean Journal of Inorganic Chemistry
Issue number18
Pages (from-to)2582-2593
ISSN1434-1948
DOIs
Publication statusPublished - 2007
Externally publishedYes

Keywords

  • Alkenes
  • Carbon monoxide
  • Palladium
  • Polyketones
  • Polymerisation
  • CHEMISTRY,
  • CO/STYRENE COPOLYMERIZATION REACTION
  • PALLADIUM-DIPHOSPHINE CATALYSIS
  • PYRIDINE-IMIDAZOLINE LIGANDS
  • DONOR CHELATING LIGANDS
  • POLAR MONOMERS
  • MECHANISTIC ASPECTS
  • CRYSTAL-STRUCTURES
  • ALPHA-OLEFINS
  • ASYMMETRIC TERPOLYMERIZATION
  • INSERTION REACTIONS
  • polymerisation
  • polyketones
  • palladium
  • carbon monoxide
  • alkenes

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