After-Effects of the Cobalt-57-Iron-57 Electron-Capture Reaction in Cobalt-57-Doped Tricadmium Bis [hexacyanoferrate (III)] Dodecahydrate

Jes Fenger, Lars A. Frees

    Research output: Contribution to journalJournal articleResearchpeer-review

    Abstract

    Mössbauer-emission spectra of cobalt-57-doped Cd3[Fe(CN)6]2, 12H2O have been recorded at various temperatures and resolved into two doublets, one symmetric for the parent [Fe(CN)6]3– and one asymmetric attributed to a square-pyradimal [Fe(CN)5]2– complex. The asymmetry vanishes with increasing temperature and thus cannot be attributed to a Goldanskii–Karyagin effect. The possibilities of paramagnetic relaxation are briefly discussed.
    Original languageEnglish
    JournalJOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
    Issue number21
    Pages (from-to)2309-2310
    ISSN0300-9246
    DOIs
    Publication statusPublished - 1974

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