Activity – or Lack Thereof – of RuO2 Based Electrodes in the Electrocatalytic Reduction of CO2

Stefano Mezzavilla*, Yu Katayama, Reshma Rao, Jonathan Hwang, Anna Regoutz, Yang Shao-Horn, Ib Chorkendorff, Ifan E. L. Stephens

*Corresponding author for this work

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

RuO2-based electrodes have been extensively studied for several electrochemical reactions. Earlier literature works claim RuO2-based catalysts to be active also for the electrocatalytic conversion of CO2 to methanol with high selectivity at very low overpotentials. Here we report a thorough investigation of RuO2 films and particles for the electrocatalytic reduction of CO2. The different experimental configurations explored in our work showed that H2 is basically the only reaction product under CO2 reduction conditions in contrast to earlier reports. In situ surface enhanced infrared absorption spectroscopy (SEIRAS) measurements revealed that CO bound to the RuO2 surface, albeit acting solely as spectator species. Our experiments indicated that adsorbed CO cannot be reduced further to methanol or other CO2 reduction products.
Original languageEnglish
JournalJournal of Physical Chemistry C
Volume123
Issue number29
Pages (from-to)17765-17773
Number of pages9
ISSN1932-7447
DOIs
Publication statusPublished - 2019

Cite this

Mezzavilla, S., Katayama, Y., Rao, R., Hwang, J., Regoutz, A., Shao-Horn, Y., ... Stephens, I. E. L. (2019). Activity – or Lack Thereof – of RuO2 Based Electrodes in the Electrocatalytic Reduction of CO2. Journal of Physical Chemistry C, 123(29), 17765-17773. https://doi.org/10.1021/acs.jpcc.9b01431
Mezzavilla, Stefano ; Katayama, Yu ; Rao, Reshma ; Hwang, Jonathan ; Regoutz, Anna ; Shao-Horn, Yang ; Chorkendorff, Ib ; Stephens, Ifan E. L. / Activity – or Lack Thereof – of RuO2 Based Electrodes in the Electrocatalytic Reduction of CO2. In: Journal of Physical Chemistry C. 2019 ; Vol. 123, No. 29. pp. 17765-17773.
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title = "Activity – or Lack Thereof – of RuO2 Based Electrodes in the Electrocatalytic Reduction of CO2",
abstract = "RuO2-based electrodes have been extensively studied for several electrochemical reactions. Earlier literature works claim RuO2-based catalysts to be active also for the electrocatalytic conversion of CO2 to methanol with high selectivity at very low overpotentials. Here we report a thorough investigation of RuO2 films and particles for the electrocatalytic reduction of CO2. The different experimental configurations explored in our work showed that H2 is basically the only reaction product under CO2 reduction conditions in contrast to earlier reports. In situ surface enhanced infrared absorption spectroscopy (SEIRAS) measurements revealed that CO bound to the RuO2 surface, albeit acting solely as spectator species. Our experiments indicated that adsorbed CO cannot be reduced further to methanol or other CO2 reduction products.",
author = "Stefano Mezzavilla and Yu Katayama and Reshma Rao and Jonathan Hwang and Anna Regoutz and Yang Shao-Horn and Ib Chorkendorff and Stephens, {Ifan E. L.}",
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Mezzavilla, S, Katayama, Y, Rao, R, Hwang, J, Regoutz, A, Shao-Horn, Y, Chorkendorff, I & Stephens, IEL 2019, 'Activity – or Lack Thereof – of RuO2 Based Electrodes in the Electrocatalytic Reduction of CO2', Journal of Physical Chemistry C, vol. 123, no. 29, pp. 17765-17773. https://doi.org/10.1021/acs.jpcc.9b01431

Activity – or Lack Thereof – of RuO2 Based Electrodes in the Electrocatalytic Reduction of CO2. / Mezzavilla, Stefano; Katayama, Yu; Rao, Reshma; Hwang, Jonathan; Regoutz, Anna; Shao-Horn, Yang; Chorkendorff, Ib; Stephens, Ifan E. L.

In: Journal of Physical Chemistry C, Vol. 123, No. 29, 2019, p. 17765-17773.

Research output: Contribution to journalJournal articleResearchpeer-review

TY - JOUR

T1 - Activity – or Lack Thereof – of RuO2 Based Electrodes in the Electrocatalytic Reduction of CO2

AU - Mezzavilla, Stefano

AU - Katayama, Yu

AU - Rao, Reshma

AU - Hwang, Jonathan

AU - Regoutz, Anna

AU - Shao-Horn, Yang

AU - Chorkendorff, Ib

AU - Stephens, Ifan E. L.

PY - 2019

Y1 - 2019

N2 - RuO2-based electrodes have been extensively studied for several electrochemical reactions. Earlier literature works claim RuO2-based catalysts to be active also for the electrocatalytic conversion of CO2 to methanol with high selectivity at very low overpotentials. Here we report a thorough investigation of RuO2 films and particles for the electrocatalytic reduction of CO2. The different experimental configurations explored in our work showed that H2 is basically the only reaction product under CO2 reduction conditions in contrast to earlier reports. In situ surface enhanced infrared absorption spectroscopy (SEIRAS) measurements revealed that CO bound to the RuO2 surface, albeit acting solely as spectator species. Our experiments indicated that adsorbed CO cannot be reduced further to methanol or other CO2 reduction products.

AB - RuO2-based electrodes have been extensively studied for several electrochemical reactions. Earlier literature works claim RuO2-based catalysts to be active also for the electrocatalytic conversion of CO2 to methanol with high selectivity at very low overpotentials. Here we report a thorough investigation of RuO2 films and particles for the electrocatalytic reduction of CO2. The different experimental configurations explored in our work showed that H2 is basically the only reaction product under CO2 reduction conditions in contrast to earlier reports. In situ surface enhanced infrared absorption spectroscopy (SEIRAS) measurements revealed that CO bound to the RuO2 surface, albeit acting solely as spectator species. Our experiments indicated that adsorbed CO cannot be reduced further to methanol or other CO2 reduction products.

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DO - 10.1021/acs.jpcc.9b01431

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