Accurate Ground-State Energies of Solids and Molecules from Time-Dependent Density-Functional Theory

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Abstract

We demonstrate that ground-state energies approaching chemical accuracy can be obtained by combining the adiabatic-connection fluctuation-dissipation theorem with time-dependent densityfunctional theory. The key ingredient is a renormalization scheme, which eliminates the divergence of the correlation hole characteristic of any local kernel. This new class of renormalized kernels gives a significantly better description of the short-range correlations in covalent bonds compared to the random phase approximation (RPA) and yields a fourfold improvement of RPA binding energies in both molecules and solids. We also consider examples of barrier heights in chemical reactions, molecular adsorption, and graphene interacting with metal surfaces, which are three examples where the RPA has been successful. In these cases, the renormalized kernel provides results that are of equal quality or even slightly better than the RPA, with a similar computational cost.
Original languageEnglish
JournalPhysical Review Letters
Volume112
Issue number20
Pages (from-to)203001
ISSN0031-9007
DOIs
Publication statusPublished - 2014

Bibliographical note

© 2014 American Physical Society

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