Absolute rate constants for the reaction of NO3 radicals with a series of dienes at 295 K

T. Ellermann; O.J. Nielsen; H. Skov

doi:10.1016/0009-2614(92)80002-S

Absolute rate constants for the reaction of NO₃ radicals with a series of dienes at 295 K

T. Ellermann, O.J. Nielsen, H. Skov

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

The rate constants for the reaction of NO3 radicals with a series of 7 dienes, 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, trans-1,3-pentadiene, cis-1,3-pentadiene, trans,trans-2,4-hexadiene, and 1,3-cyclohexadiene, were measured at 295 K and at a total pressure of 1 atm. The rate constant were obtained using the absolute technique of pulse radiolysis combined with kinetic UV-VIS spectroscopy. The results are discussed in terms of reactivity trends and previous literature data.

Original language	English
Journal	Chemical Physics Letters
Volume	200
Issue number	3-4
Pages (from-to)	224-229
ISSN	0009-2614
DOIs	https://doi.org/10.1016/0009-2614(92)80002-S
Publication status	Published - Dec 1992

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title = "Absolute rate constants for the reaction of NO3 radicals with a series of dienes at 295 K",

abstract = "The rate constants for the reaction of NO3 radicals with a series of 7 dienes, 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, trans-1,3-pentadiene, cis-1,3-pentadiene, trans,trans-2,4-hexadiene, and 1,3-cyclohexadiene, were measured at 295 K and at a total pressure of 1 atm. The rate constant were obtained using the absolute technique of pulse radiolysis combined with kinetic UV-VIS spectroscopy. The results are discussed in terms of reactivity trends and previous literature data.",

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T1 - Absolute rate constants for the reaction of NO3 radicals with a series of dienes at 295 K

AU - Ellermann, T.

AU - Nielsen, O.J.

AU - Skov, H.

PY - 1992/12

Y1 - 1992/12

N2 - The rate constants for the reaction of NO3 radicals with a series of 7 dienes, 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, trans-1,3-pentadiene, cis-1,3-pentadiene, trans,trans-2,4-hexadiene, and 1,3-cyclohexadiene, were measured at 295 K and at a total pressure of 1 atm. The rate constant were obtained using the absolute technique of pulse radiolysis combined with kinetic UV-VIS spectroscopy. The results are discussed in terms of reactivity trends and previous literature data.

AB - The rate constants for the reaction of NO3 radicals with a series of 7 dienes, 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, trans-1,3-pentadiene, cis-1,3-pentadiene, trans,trans-2,4-hexadiene, and 1,3-cyclohexadiene, were measured at 295 K and at a total pressure of 1 atm. The rate constant were obtained using the absolute technique of pulse radiolysis combined with kinetic UV-VIS spectroscopy. The results are discussed in terms of reactivity trends and previous literature data.

KW - Virkning af forurening

U2 - 10.1016/0009-2614(92)80002-S

DO - 10.1016/0009-2614(92)80002-S

M3 - Journal article

VL - 200

SP - 224

EP - 229

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 3-4