The rate constants for the reaction of NO3 radicals with a series of 7 dienes, 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, trans-1,3-pentadiene, cis-1,3-pentadiene, trans,trans-2,4-hexadiene, and 1,3-cyclohexadiene, were measured at 295 K and at a total pressure of 1 atm. The rate constant were obtained using the absolute technique of pulse radiolysis combined with kinetic UV-VIS spectroscopy. The results are discussed in terms of reactivity trends and previous literature data.
Ellermann, T., Nielsen, O. J., & Skov, H. (1992). Absolute rate constants for the reaction of NO3 radicals with a series of dienes at 295 K. Chemical Physics Letters, 200(3-4), 224-229. https://doi.org/10.1016/0009-2614(92)80002-S