Absolute rate constants for the reaction of NO3 radicals with a series of dienes at 295 K

T. Ellermann, O.J. Nielsen, H. Skov

    Research output: Contribution to journalJournal articleResearchpeer-review

    Abstract

    The rate constants for the reaction of NO3 radicals with a series of 7 dienes, 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, trans-1,3-pentadiene, cis-1,3-pentadiene, trans,trans-2,4-hexadiene, and 1,3-cyclohexadiene, were measured at 295 K and at a total pressure of 1 atm. The rate constant were obtained using the absolute technique of pulse radiolysis combined with kinetic UV-VIS spectroscopy. The results are discussed in terms of reactivity trends and previous literature data.
    Original languageEnglish
    JournalChemical Physics Letters
    Volume200
    Issue number3-4
    Pages (from-to)224-229
    ISSN0009-2614
    DOIs
    Publication statusPublished - Dec 1992

    Cite this