A thermo-reversible silicone elastomer with remotely controlled self-healing

E. Ogliani, L. Yu, I. Javakhishvili, A. L. Skov*

*Corresponding author for this work

Research output: Contribution to journalJournal articleResearchpeer-review

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Abstract

Soft thermoplastic elastomers with increased durability and reliability are in high demand for a broad spectrum of applications. Silicone elastomers are soft and durable, but they are not thermoplastic in nature, and under extreme conditions such as high voltage or large deformations, reliability may also suffer. Thus, as a solution to these shortcomings, which are typical of silicone elastomers, it is natural to propose a thermo-reversible, self-healing, and recyclable silicone-based elastomer. Stimuli-responsivity is imparted to the silicone polymer by incorporating supramolecular 2-ureido-4[1H]-pyrimidone (UPy) self-assembling motifs via free radical polymerisation. Self-healing of the novel elastomer may be triggered by both direct and indirect heating, the latter by means of incorporating Fe3O4 particles into the elastomer and subsequent exposure to an alternating magnetic field. As a consequence of temperature responsiveness and high thermal stability, the elastomer is proven recyclable, by withstanding multiple reprocessing procedures with no substantial effects on the resulting properties. The synergy of these valuable characteristics makes this novel material a smart candidate for innumerable applications where soft and reliable elastomers are sought.
Original languageEnglish
JournalR S C Advances
Volume8
Issue number15
Pages (from-to)8285-8291
ISSN2046-2069
DOIs
Publication statusPublished - 2018

Bibliographical note

Open Access Article. Published on 22 February 2018. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Cite this

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title = "A thermo-reversible silicone elastomer with remotely controlled self-healing",
abstract = "Soft thermoplastic elastomers with increased durability and reliability are in high demand for a broad spectrum of applications. Silicone elastomers are soft and durable, but they are not thermoplastic in nature, and under extreme conditions such as high voltage or large deformations, reliability may also suffer. Thus, as a solution to these shortcomings, which are typical of silicone elastomers, it is natural to propose a thermo-reversible, self-healing, and recyclable silicone-based elastomer. Stimuli-responsivity is imparted to the silicone polymer by incorporating supramolecular 2-ureido-4[1H]-pyrimidone (UPy) self-assembling motifs via free radical polymerisation. Self-healing of the novel elastomer may be triggered by both direct and indirect heating, the latter by means of incorporating Fe3O4 particles into the elastomer and subsequent exposure to an alternating magnetic field. As a consequence of temperature responsiveness and high thermal stability, the elastomer is proven recyclable, by withstanding multiple reprocessing procedures with no substantial effects on the resulting properties. The synergy of these valuable characteristics makes this novel material a smart candidate for innumerable applications where soft and reliable elastomers are sought.",
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A thermo-reversible silicone elastomer with remotely controlled self-healing. / Ogliani, E.; Yu, L.; Javakhishvili, I.; Skov, A. L.

In: R S C Advances, Vol. 8, No. 15, 2018, p. 8285-8291.

Research output: Contribution to journalJournal articleResearchpeer-review

TY - JOUR

T1 - A thermo-reversible silicone elastomer with remotely controlled self-healing

AU - Ogliani, E.

AU - Yu, L.

AU - Javakhishvili, I.

AU - Skov, A. L.

N1 - Open Access Article. Published on 22 February 2018. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

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N2 - Soft thermoplastic elastomers with increased durability and reliability are in high demand for a broad spectrum of applications. Silicone elastomers are soft and durable, but they are not thermoplastic in nature, and under extreme conditions such as high voltage or large deformations, reliability may also suffer. Thus, as a solution to these shortcomings, which are typical of silicone elastomers, it is natural to propose a thermo-reversible, self-healing, and recyclable silicone-based elastomer. Stimuli-responsivity is imparted to the silicone polymer by incorporating supramolecular 2-ureido-4[1H]-pyrimidone (UPy) self-assembling motifs via free radical polymerisation. Self-healing of the novel elastomer may be triggered by both direct and indirect heating, the latter by means of incorporating Fe3O4 particles into the elastomer and subsequent exposure to an alternating magnetic field. As a consequence of temperature responsiveness and high thermal stability, the elastomer is proven recyclable, by withstanding multiple reprocessing procedures with no substantial effects on the resulting properties. The synergy of these valuable characteristics makes this novel material a smart candidate for innumerable applications where soft and reliable elastomers are sought.

AB - Soft thermoplastic elastomers with increased durability and reliability are in high demand for a broad spectrum of applications. Silicone elastomers are soft and durable, but they are not thermoplastic in nature, and under extreme conditions such as high voltage or large deformations, reliability may also suffer. Thus, as a solution to these shortcomings, which are typical of silicone elastomers, it is natural to propose a thermo-reversible, self-healing, and recyclable silicone-based elastomer. Stimuli-responsivity is imparted to the silicone polymer by incorporating supramolecular 2-ureido-4[1H]-pyrimidone (UPy) self-assembling motifs via free radical polymerisation. Self-healing of the novel elastomer may be triggered by both direct and indirect heating, the latter by means of incorporating Fe3O4 particles into the elastomer and subsequent exposure to an alternating magnetic field. As a consequence of temperature responsiveness and high thermal stability, the elastomer is proven recyclable, by withstanding multiple reprocessing procedures with no substantial effects on the resulting properties. The synergy of these valuable characteristics makes this novel material a smart candidate for innumerable applications where soft and reliable elastomers are sought.

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