A simple protocol to enhance the recycling properties of amphiphilic rhodium hydroformylation catalysts

Magnus Karlsson; Carlaxel Andersson

doi:10.1016/S1566-7367(01)00066-8

A simple protocol to enhance the recycling properties of amphiphilic rhodium hydroformylation catalysts

Magnus Karlsson
, Carlaxel Andersson

Lund University

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

The recyclability of the hydroformylation catalysts employing Rh(I) and the amphiphilic N3P ligand ({4-[Bis(2-diethylaminoethyl)aminomethyl)diphenyl}phosphine) is greatly improved by using HCl(aq) in the aqueous extraction and subsequent anion metathesis with NaBPh4. (C) 2002 Elsevier Science B.V. All rights reserved.

Original language	English
Journal	Catalysis Communications
Volume	3
Issue number	1
Pages (from-to)	1-5
ISSN	1566-7367
DOIs	https://doi.org/10.1016/S1566-7367(01)00066-8
Publication status	Published - 2002
Externally published	Yes

Keywords

Catalysis
Process Chemistry and Technology
Complexation
Curve fitting
Extraction
Negative ions
pH effects
Recycling
Rhodium
Solutions
Hydroformylation
Ligands
Catalysts
CHEMISTRY,
COMPLEXES
TRIPHENYLPHOSPHINE
HYDROGENATION
OLEFINS
LIGANDS
PH
T

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title = "A simple protocol to enhance the recycling properties of amphiphilic rhodium hydroformylation catalysts",

abstract = "The recyclability of the hydroformylation catalysts employing Rh(I) and the amphiphilic N3P ligand (\{4-[Bis(2-diethylaminoethyl)aminomethyl)diphenyl\}phosphine) is greatly improved by using HCl(aq) in the aqueous extraction and subsequent anion metathesis with NaBPh4. (C) 2002 Elsevier Science B.V. All rights reserved.",

keywords = "Catalysis, Process Chemistry and Technology, Complexation, Curve fitting, Extraction, Negative ions, pH effects, Recycling, Rhodium, Solutions, Hydroformylation, Ligands, Catalysts, CHEMISTRY,, COMPLEXES, TRIPHENYLPHOSPHINE, HYDROGENATION, OLEFINS, LIGANDS, PH, T",

author = "Magnus Karlsson and Carlaxel Andersson",

year = "2002",

doi = "10.1016/S1566-7367(01)00066-8",

language = "English",

volume = "3",

pages = "1--5",

journal = "Catalysis Communications",

issn = "1566-7367",

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TY - JOUR

T1 - A simple protocol to enhance the recycling properties of amphiphilic rhodium hydroformylation catalysts

AU - Karlsson, Magnus

AU - Andersson, Carlaxel

PY - 2002

Y1 - 2002

N2 - The recyclability of the hydroformylation catalysts employing Rh(I) and the amphiphilic N3P ligand ({4-[Bis(2-diethylaminoethyl)aminomethyl)diphenyl}phosphine) is greatly improved by using HCl(aq) in the aqueous extraction and subsequent anion metathesis with NaBPh4. (C) 2002 Elsevier Science B.V. All rights reserved.

AB - The recyclability of the hydroformylation catalysts employing Rh(I) and the amphiphilic N3P ligand ({4-[Bis(2-diethylaminoethyl)aminomethyl)diphenyl}phosphine) is greatly improved by using HCl(aq) in the aqueous extraction and subsequent anion metathesis with NaBPh4. (C) 2002 Elsevier Science B.V. All rights reserved.

KW - Catalysis

KW - Process Chemistry and Technology

KW - Complexation

KW - Curve fitting

KW - Extraction

KW - Negative ions

KW - pH effects

KW - Recycling

KW - Rhodium

KW - Solutions

KW - Hydroformylation

KW - Ligands

KW - Catalysts

KW - CHEMISTRY,

KW - COMPLEXES

KW - TRIPHENYLPHOSPHINE

KW - HYDROGENATION

KW - OLEFINS

KW - LIGANDS

KW - PH

KW - T

U2 - 10.1016/S1566-7367(01)00066-8

DO - 10.1016/S1566-7367(01)00066-8

M3 - Journal article

SN - 1566-7367

VL - 3

SP - 1

EP - 5

JO - Catalysis Communications

JF - Catalysis Communications

IS - 1

ER -

A simple protocol to enhance the recycling properties of amphiphilic rhodium hydroformylation catalysts

Abstract

Keywords

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