A Polyphenylene Support for Pd Catalysts with Exceptional Catalytic Activity

Feng Wang; Jerrik Jørgen Mielby; Felix Herrmann Richter; Guanghui Wang; Gonzalo Prieto; Takeshi Kasama; Claudia Weidenthaler; Hans-Josef Bongard; Søren Kegnæs; Alois Fuerstner; Ferdi Schueth

doi:10.1002/anie.201404912

A Polyphenylene Support for Pd Catalysts with Exceptional Catalytic Activity

Feng Wang
, Jerrik Jørgen Mielby
, Felix Herrmann Richter
, Guanghui Wang
, Gonzalo Prieto
, Takeshi Kasama
, Claudia Weidenthaler
, Hans-Josef Bongard
, Søren Kegnæs
, Alois Fuerstner
, Ferdi Schueth

Department of Chemistry

Max Planck Institute

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

We describe a solid polyphenylene support that serves as an excellent platform for metal-catalyzed reactions that are normally carried out under homogeneous conditions. The catalyst is synthesized by palladium-catalyzed Suzuki coupling which directly results in formation of palladium nanoparticles confined to a porous polyphenylene network. The composite solid is in turn highly active for further Suzuki coupling reactions, including non-activated substrates that are challenging even for molecular catalysts.

Original language	English
Journal	Angewandte chemie-international edition
Volume	53
Issue number	33
Pages (from-to)	8645-8648
ISSN	1433-7851
DOIs	https://doi.org/10.1002/anie.201404912
Publication status	Published - 2014

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title = "A Polyphenylene Support for Pd Catalysts with Exceptional Catalytic Activity",

abstract = "We describe a solid polyphenylene support that serves as an excellent platform for metal-catalyzed reactions that are normally carried out under homogeneous conditions. The catalyst is synthesized by palladium-catalyzed Suzuki coupling which directly results in formation of palladium nanoparticles confined to a porous polyphenylene network. The composite solid is in turn highly active for further Suzuki coupling reactions, including non-activated substrates that are challenging even for molecular catalysts.",

author = "Feng Wang and Mielby, \{Jerrik J{\o}rgen\} and Richter, \{Felix Herrmann\} and Guanghui Wang and Gonzalo Prieto and Takeshi Kasama and Claudia Weidenthaler and Hans-Josef Bongard and S{\o}ren Kegn{\ae}s and Alois Fuerstner and Ferdi Schueth",

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doi = "10.1002/anie.201404912",

language = "English",

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TY - JOUR

T1 - A Polyphenylene Support for Pd Catalysts with Exceptional Catalytic Activity

AU - Wang, Feng

AU - Mielby, Jerrik Jørgen

AU - Richter, Felix Herrmann

AU - Wang, Guanghui

AU - Prieto, Gonzalo

AU - Kasama, Takeshi

AU - Weidenthaler, Claudia

AU - Bongard, Hans-Josef

AU - Kegnæs, Søren

AU - Fuerstner, Alois

AU - Schueth, Ferdi

PY - 2014

Y1 - 2014

N2 - We describe a solid polyphenylene support that serves as an excellent platform for metal-catalyzed reactions that are normally carried out under homogeneous conditions. The catalyst is synthesized by palladium-catalyzed Suzuki coupling which directly results in formation of palladium nanoparticles confined to a porous polyphenylene network. The composite solid is in turn highly active for further Suzuki coupling reactions, including non-activated substrates that are challenging even for molecular catalysts.

AB - We describe a solid polyphenylene support that serves as an excellent platform for metal-catalyzed reactions that are normally carried out under homogeneous conditions. The catalyst is synthesized by palladium-catalyzed Suzuki coupling which directly results in formation of palladium nanoparticles confined to a porous polyphenylene network. The composite solid is in turn highly active for further Suzuki coupling reactions, including non-activated substrates that are challenging even for molecular catalysts.

U2 - 10.1002/anie.201404912

DO - 10.1002/anie.201404912

M3 - Journal article

C2 - 25044615

SN - 1433-7851

VL - 53

SP - 8645

EP - 8648

JO - Angewandte chemie-international edition

JF - Angewandte chemie-international edition

IS - 33

ER -

A Polyphenylene Support for Pd Catalysts with Exceptional Catalytic Activity

Abstract

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