A Polyphenylene Support for Pd Catalysts with Exceptional Catalytic Activity

Feng Wang, Jerrik Jørgen Mielby, Felix Herrmann Richter, Guanghui Wang, Gonzalo Prieto, Takeshi Kasama, Claudia Weidenthaler, Hans-Josef Bongard, Søren Kegnæs, Alois Fuerstner, Ferdi Schueth

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

We describe a solid polyphenylene support that serves as an excellent platform for metal-catalyzed reactions that are normally carried out under homogeneous conditions. The catalyst is synthesized by palladium-catalyzed Suzuki coupling which directly results in formation of palladium nanoparticles confined to a porous polyphenylene network. The composite solid is in turn highly active for further Suzuki coupling reactions, including non-activated substrates that are challenging even for molecular catalysts.
Original languageEnglish
JournalAngewandte chemie-international edition
Volume53
Issue number33
Pages (from-to)8645-8648
ISSN1433-7851
DOIs
Publication statusPublished - 2014

Cite this

Wang, Feng ; Mielby, Jerrik Jørgen ; Richter, Felix Herrmann ; Wang, Guanghui ; Prieto, Gonzalo ; Kasama, Takeshi ; Weidenthaler, Claudia ; Bongard, Hans-Josef ; Kegnæs, Søren ; Fuerstner, Alois ; Schueth, Ferdi. / A Polyphenylene Support for Pd Catalysts with Exceptional Catalytic Activity. In: Angewandte chemie-international edition. 2014 ; Vol. 53, No. 33. pp. 8645-8648.
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abstract = "We describe a solid polyphenylene support that serves as an excellent platform for metal-catalyzed reactions that are normally carried out under homogeneous conditions. The catalyst is synthesized by palladium-catalyzed Suzuki coupling which directly results in formation of palladium nanoparticles confined to a porous polyphenylene network. The composite solid is in turn highly active for further Suzuki coupling reactions, including non-activated substrates that are challenging even for molecular catalysts.",
author = "Feng Wang and Mielby, {Jerrik J{\o}rgen} and Richter, {Felix Herrmann} and Guanghui Wang and Gonzalo Prieto and Takeshi Kasama and Claudia Weidenthaler and Hans-Josef Bongard and S{\o}ren Kegn{\ae}s and Alois Fuerstner and Ferdi Schueth",
year = "2014",
doi = "10.1002/anie.201404912",
language = "English",
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pages = "8645--8648",
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Wang, F, Mielby, JJ, Richter, FH, Wang, G, Prieto, G, Kasama, T, Weidenthaler, C, Bongard, H-J, Kegnæs, S, Fuerstner, A & Schueth, F 2014, 'A Polyphenylene Support for Pd Catalysts with Exceptional Catalytic Activity', Angewandte chemie-international edition, vol. 53, no. 33, pp. 8645-8648. https://doi.org/10.1002/anie.201404912

A Polyphenylene Support for Pd Catalysts with Exceptional Catalytic Activity. / Wang, Feng; Mielby, Jerrik Jørgen; Richter, Felix Herrmann; Wang, Guanghui; Prieto, Gonzalo; Kasama, Takeshi; Weidenthaler, Claudia; Bongard, Hans-Josef; Kegnæs, Søren; Fuerstner, Alois; Schueth, Ferdi.

In: Angewandte chemie-international edition, Vol. 53, No. 33, 2014, p. 8645-8648.

Research output: Contribution to journalJournal articleResearchpeer-review

TY - JOUR

T1 - A Polyphenylene Support for Pd Catalysts with Exceptional Catalytic Activity

AU - Wang, Feng

AU - Mielby, Jerrik Jørgen

AU - Richter, Felix Herrmann

AU - Wang, Guanghui

AU - Prieto, Gonzalo

AU - Kasama, Takeshi

AU - Weidenthaler, Claudia

AU - Bongard, Hans-Josef

AU - Kegnæs, Søren

AU - Fuerstner, Alois

AU - Schueth, Ferdi

PY - 2014

Y1 - 2014

N2 - We describe a solid polyphenylene support that serves as an excellent platform for metal-catalyzed reactions that are normally carried out under homogeneous conditions. The catalyst is synthesized by palladium-catalyzed Suzuki coupling which directly results in formation of palladium nanoparticles confined to a porous polyphenylene network. The composite solid is in turn highly active for further Suzuki coupling reactions, including non-activated substrates that are challenging even for molecular catalysts.

AB - We describe a solid polyphenylene support that serves as an excellent platform for metal-catalyzed reactions that are normally carried out under homogeneous conditions. The catalyst is synthesized by palladium-catalyzed Suzuki coupling which directly results in formation of palladium nanoparticles confined to a porous polyphenylene network. The composite solid is in turn highly active for further Suzuki coupling reactions, including non-activated substrates that are challenging even for molecular catalysts.

U2 - 10.1002/anie.201404912

DO - 10.1002/anie.201404912

M3 - Journal article

VL - 53

SP - 8645

EP - 8648

JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

SN - 1433-7851

IS - 33

ER -