TY - JOUR
T1 - A Polyphenylene Support for Pd Catalysts with Exceptional Catalytic Activity
AU - Wang, Feng
AU - Mielby, Jerrik Jørgen
AU - Richter, Felix Herrmann
AU - Wang, Guanghui
AU - Prieto, Gonzalo
AU - Kasama, Takeshi
AU - Weidenthaler, Claudia
AU - Bongard, Hans-Josef
AU - Kegnæs, Søren
AU - Fuerstner, Alois
AU - Schueth, Ferdi
PY - 2014
Y1 - 2014
N2 - We describe a solid polyphenylene support that serves as an excellent platform for metal-catalyzed reactions that are normally carried out under homogeneous conditions. The catalyst is synthesized by palladium-catalyzed Suzuki coupling which directly results in formation of palladium nanoparticles confined to a porous polyphenylene network. The composite solid is in turn highly active for further Suzuki coupling reactions, including non-activated substrates that are challenging even for molecular catalysts.
AB - We describe a solid polyphenylene support that serves as an excellent platform for metal-catalyzed reactions that are normally carried out under homogeneous conditions. The catalyst is synthesized by palladium-catalyzed Suzuki coupling which directly results in formation of palladium nanoparticles confined to a porous polyphenylene network. The composite solid is in turn highly active for further Suzuki coupling reactions, including non-activated substrates that are challenging even for molecular catalysts.
U2 - 10.1002/anie.201404912
DO - 10.1002/anie.201404912
M3 - Journal article
C2 - 25044615
SN - 1433-7851
VL - 53
SP - 8645
EP - 8648
JO - Angewandte chemie-international edition
JF - Angewandte chemie-international edition
IS - 33
ER -