A Photoelectron Spectroscopic Study of Di-t-butylphosphazene

S. Elbel; A. Ellis; E. Niecke; Helge Egsgaard; Lars Carlsen

doi:10.1039/DT9850000879

A Photoelectron Spectroscopic Study of Di-t-butylphosphazene

S. Elbel, A. Ellis, E. Niecke, Helge Egsgaard, Lars Carlsen

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Abstract

Gaseous trans-ButPNBut, generated by mild gas-phase thermolysis of its more stable [2 + 1] cyclodimer, has been characterized by field-ionization mass spectrometry and U.V. photoelectron spectroscopy. The photoelectron spectrum has been assigned based on SCC-Xα model calculations for representative H EEH and E2 molecules (E2= N2, PN, or P2) and by comparison with the known ionization potentials of RNNR and E2 species. The low-energy sequence for parent dialkyldiphosphenes is deduced.

Original language	English
Journal	Dalton Transactions (Print Edition)
Issue number	5
Pages (from-to)	879-884
ISSN	1477-9226
DOIs	https://doi.org/10.1039/DT9850000879
Publication status	Published - 1985

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title = "A Photoelectron Spectroscopic Study of Di-t-butylphosphazene",

abstract = "Gaseous trans-ButPNBut, generated by mild gas-phase thermolysis of its more stable [2 + 1] cyclodimer, has been characterized by field-ionization mass spectrometry and U.V. photoelectron spectroscopy. The photoelectron spectrum has been assigned based on SCC-Xα model calculations for representative H EEH and E2 molecules (E2= N2, PN, or P2) and by comparison with the known ionization potentials of RNNR and E2 species. The low-energy sequence for parent dialkyldiphosphenes is deduced.",

author = "S. Elbel and A. Ellis and E. Niecke and Helge Egsgaard and Lars Carlsen",

year = "1985",

doi = "10.1039/DT9850000879",

language = "English",

pages = "879--884",

journal = "Dalton Transactions (Print Edition)",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "5",

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T1 - A Photoelectron Spectroscopic Study of Di-t-butylphosphazene

AU - Elbel, S.

AU - Ellis, A.

AU - Niecke, E.

AU - Egsgaard, Helge

AU - Carlsen, Lars

PY - 1985

Y1 - 1985

N2 - Gaseous trans-ButPNBut, generated by mild gas-phase thermolysis of its more stable [2 + 1] cyclodimer, has been characterized by field-ionization mass spectrometry and U.V. photoelectron spectroscopy. The photoelectron spectrum has been assigned based on SCC-Xα model calculations for representative H EEH and E2 molecules (E2= N2, PN, or P2) and by comparison with the known ionization potentials of RNNR and E2 species. The low-energy sequence for parent dialkyldiphosphenes is deduced.

AB - Gaseous trans-ButPNBut, generated by mild gas-phase thermolysis of its more stable [2 + 1] cyclodimer, has been characterized by field-ionization mass spectrometry and U.V. photoelectron spectroscopy. The photoelectron spectrum has been assigned based on SCC-Xα model calculations for representative H EEH and E2 molecules (E2= N2, PN, or P2) and by comparison with the known ionization potentials of RNNR and E2 species. The low-energy sequence for parent dialkyldiphosphenes is deduced.

U2 - 10.1039/DT9850000879

DO - 10.1039/DT9850000879

M3 - Journal article

SN - 1477-9226

SP - 879

EP - 884

JO - Dalton Transactions (Print Edition)

JF - Dalton Transactions (Print Edition)

IS - 5

ER -

A Photoelectron Spectroscopic Study of Di-t-butylphosphazene

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