A phase-transfer crystallization pathway to synthesize ultrasmall silicoaluminophosphate for enhanced catalytic conversion of dimethylether-to-olefin

Hongxin Ding; Jiajia Ding; Wei Liu; Xiaoling Zhao; Qijin Chi; Kake Zhu; Xinggui Zhou; Weimin Yang

doi:10.1039/C8CE01752B

A phase-transfer crystallization pathway to synthesize ultrasmall silicoaluminophosphate for enhanced catalytic conversion of dimethylether-to-olefin

Hongxin Ding, Jiajia Ding, Wei Liu, Xiaoling Zhao, Qijin Chi, Kake Zhu^*, Xinggui Zhou, Weimin Yang

^*Corresponding author for this work

Department of Chemistry

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

We present a phase-transfer crystallization approach to the synthesis of ultrasmall (<100 nm) SAPO-34 crystallites. This method features porogen-free and tumbling crystallization in biphasic toluene-water media. The nanosized SAPO-34 catalyst has demonstrated prolonged catalysis lifetime (approximately 5 fold) and higher ethylene/propylene selectivity (by ca. 5%) for dimethylether-to-olefin conversion.

Original language	English
Journal	CrystEngComm
Volume	21
Issue number	4
Pages (from-to)	577-582
Number of pages	6
ISSN	1466-8033
DOIs	https://doi.org/10.1039/C8CE01752B
Publication status	Published - 2019

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title = "A phase-transfer crystallization pathway to synthesize ultrasmall silicoaluminophosphate for enhanced catalytic conversion of dimethylether-to-olefin",

abstract = "We present a phase-transfer crystallization approach to the synthesis of ultrasmall (<100 nm) SAPO-34 crystallites. This method features porogen-free and tumbling crystallization in biphasic toluene-water media. The nanosized SAPO-34 catalyst has demonstrated prolonged catalysis lifetime (approximately 5 fold) and higher ethylene/propylene selectivity (by ca. 5%) for dimethylether-to-olefin conversion.",

author = "Hongxin Ding and Jiajia Ding and Wei Liu and Xiaoling Zhao and Qijin Chi and Kake Zhu and Xinggui Zhou and Weimin Yang",

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volume = "21",

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T1 - A phase-transfer crystallization pathway to synthesize ultrasmall silicoaluminophosphate for enhanced catalytic conversion of dimethylether-to-olefin

AU - Ding, Hongxin

AU - Ding, Jiajia

AU - Liu, Wei

AU - Zhao, Xiaoling

AU - Chi, Qijin

AU - Zhu, Kake

AU - Zhou, Xinggui

AU - Yang, Weimin

PY - 2019

Y1 - 2019

N2 - We present a phase-transfer crystallization approach to the synthesis of ultrasmall (<100 nm) SAPO-34 crystallites. This method features porogen-free and tumbling crystallization in biphasic toluene-water media. The nanosized SAPO-34 catalyst has demonstrated prolonged catalysis lifetime (approximately 5 fold) and higher ethylene/propylene selectivity (by ca. 5%) for dimethylether-to-olefin conversion.

AB - We present a phase-transfer crystallization approach to the synthesis of ultrasmall (<100 nm) SAPO-34 crystallites. This method features porogen-free and tumbling crystallization in biphasic toluene-water media. The nanosized SAPO-34 catalyst has demonstrated prolonged catalysis lifetime (approximately 5 fold) and higher ethylene/propylene selectivity (by ca. 5%) for dimethylether-to-olefin conversion.

U2 - 10.1039/C8CE01752B

DO - 10.1039/C8CE01752B

M3 - Journal article

AN - SCOPUS:85060273362

SN - 1466-8033

VL - 21

SP - 577

EP - 582

JO - CrystEngComm

JF - CrystEngComm

IS - 4

ER -

A phase-transfer crystallization pathway to synthesize ultrasmall silicoaluminophosphate for enhanced catalytic conversion of dimethylether-to-olefin

Abstract

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