A new synthesis of aliphatic isothiocyanates from primary amines, convenient for in situ use

Ulrik Boas; M. H. Jakobsen

doi:10.1039/C39950001995

A new synthesis of aliphatic isothiocyanates from primary amines, convenient for in situ use

Ulrik Boas, M. H. Jakobsen

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

Primary aliphatic amines react with carbon disulfide in the presence of BOP (benzotriazole-1-yl-oxy-tris(dimethylamino)phosphonium hexafluorophosphate 1, giving the corresponding isothiocyanates in good to high yields and high purity; a number of isothiocyanates are synthesized and isolated or generated in situ and treated with a nucleophile.

Original language	English
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	19
Pages (from-to)	1995-1996
ISSN	0022-4936
DOIs	https://doi.org/10.1039/C39950001995
Publication status	Published - 1995

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title = "A new synthesis of aliphatic isothiocyanates from primary amines, convenient for in situ use",

abstract = "Primary aliphatic amines react with carbon disulfide in the presence of BOP (benzotriazole-1-yl-oxy-tris(dimethylamino)phosphonium hexafluorophosphate 1, giving the corresponding isothiocyanates in good to high yields and high purity; a number of isothiocyanates are synthesized and isolated or generated in situ and treated with a nucleophile.",

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year = "1995",

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journal = "Journal of the Chemical Society D: Chemical Communications",

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T1 - A new synthesis of aliphatic isothiocyanates from primary amines, convenient for in situ use

AU - Boas, Ulrik

AU - Jakobsen, M. H.

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Y1 - 1995

N2 - Primary aliphatic amines react with carbon disulfide in the presence of BOP (benzotriazole-1-yl-oxy-tris(dimethylamino)phosphonium hexafluorophosphate 1, giving the corresponding isothiocyanates in good to high yields and high purity; a number of isothiocyanates are synthesized and isolated or generated in situ and treated with a nucleophile.

AB - Primary aliphatic amines react with carbon disulfide in the presence of BOP (benzotriazole-1-yl-oxy-tris(dimethylamino)phosphonium hexafluorophosphate 1, giving the corresponding isothiocyanates in good to high yields and high purity; a number of isothiocyanates are synthesized and isolated or generated in situ and treated with a nucleophile.

U2 - 10.1039/C39950001995

DO - 10.1039/C39950001995

M3 - Journal article

SN - 0022-4936

SP - 1995

EP - 1996

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 19

ER -

A new synthesis of aliphatic isothiocyanates from primary amines, convenient for in situ use

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