A new prearranged tripodant ligand ¤N,N',N''¤-trimethyl-¤N,N',N''¤tris(3-pyridyl)-1,3,5-benzene tricarboxamide is easily obtained via the ¤N¤-methyl amide effect

M. Jørgensen, Frederik C Krebs

    Research output: Contribution to journalJournal articleResearchpeer-review

    Abstract

    The N-methyl amide cis generating effect has been utilised to create a new prearranged tripodant ligand in two synthetic steps from benzene-1,3,5-tricarbuxylic acid. Crystals of rhc ligand itself and of complexes with metal sails such as silver(I) triflate, copper(I) and copper(II) chloride and ruthenium(II) chloride have been prepared and the crystal structures solved by analysis of X-ray diffraction data. (C) 2001 Elsevier Science Ltd. All rights reserved.
    Original languageEnglish
    JournalTetrahedron Letters
    Volume42
    Issue number28
    Pages (from-to)4717-4720
    ISSN0040-4039
    DOIs
    Publication statusPublished - 2001

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