A New Look at the Stability of Dimethyl Sulfoxide and Acetonitrile in Li-O2 Batteries

Reza Younesi; Poul Norby; Tejs Vegge

doi:10.1149/2.001403eel

A New Look at the Stability of Dimethyl Sulfoxide and Acetonitrile in Li-O2 Batteries

Reza Younesi, Poul Norby, Tejs Vegge

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Abstract

Dimethyl sulfoxide (DMSO) and acetonitrile (MeCN) have recently been highlighted as promising electrolyte solvents for Li-O2 batteries. Possible reactions between these two solvents and Li2O2 are here discussed using X-ray photoelectron spectroscopy to analyze surface of the Li2O2 powder after direct contact with the solvents for different times of exposure. The results indicated that Li2O2 decomposes DMSO solvents, whereas no indication of degradation of MeCN by Li2O2 was observed.
© 2014 The Electrochemical Society.

Original language	English
Journal	E C S Electrochemistry Letters
Volume	3
Pages (from-to)	A15-A18
ISSN	1099-0062
DOIs	https://doi.org/10.1149/2.001403eel
Publication status	Published - 2014
Event	224th Electrochemical Society Meeting - The Hilton San Francisco Hotel, San Francisco, CA, United States Duration: 27 Oct 2013 → 1 Nov 2013 Conference number: 224 http://www.electrochem.org/meetings/biannual/224/

Conference

Conference	224th Electrochemical Society Meeting
Number	224
Location	The Hilton San Francisco Hotel
Country/Territory	United States
City	San Francisco, CA
Period	27/10/2013 → 01/11/2013
Internet address	http://www.electrochem.org/meetings/biannual/224/

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@article{e8bc1783dca6409ba1042169b0ee65bb,

title = "A New Look at the Stability of Dimethyl Sulfoxide and Acetonitrile in Li-O2 Batteries",

abstract = "Dimethyl sulfoxide (DMSO) and acetonitrile (MeCN) have recently been highlighted as promising electrolyte solvents for Li-O2 batteries. Possible reactions between these two solvents and Li2O2 are here discussed using X-ray photoelectron spectroscopy to analyze surface of the Li2O2 powder after direct contact with the solvents for different times of exposure. The results indicated that Li2O2 decomposes DMSO solvents, whereas no indication of degradation of MeCN by Li2O2 was observed.{\textcopyright} 2014 The Electrochemical Society.",

author = "Reza Younesi and Poul Norby and Tejs Vegge",

year = "2014",

doi = "10.1149/2.001403eel",

language = "English",

volume = "3",

pages = "A15--A18",

journal = "Electrochemical and Solid-State Letters",

issn = "1099-0062",

publisher = "The Electrochemical Society",

note = "224th Electrochemical Society Meeting , ECS ; Conference date: 27-10-2013 Through 01-11-2013",

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TY - JOUR

T1 - A New Look at the Stability of Dimethyl Sulfoxide and Acetonitrile in Li-O2 Batteries

AU - Younesi, Reza

AU - Norby, Poul

AU - Vegge, Tejs

N1 - Conference code: 224

PY - 2014

Y1 - 2014

N2 - Dimethyl sulfoxide (DMSO) and acetonitrile (MeCN) have recently been highlighted as promising electrolyte solvents for Li-O2 batteries. Possible reactions between these two solvents and Li2O2 are here discussed using X-ray photoelectron spectroscopy to analyze surface of the Li2O2 powder after direct contact with the solvents for different times of exposure. The results indicated that Li2O2 decomposes DMSO solvents, whereas no indication of degradation of MeCN by Li2O2 was observed.© 2014 The Electrochemical Society.

AB - Dimethyl sulfoxide (DMSO) and acetonitrile (MeCN) have recently been highlighted as promising electrolyte solvents for Li-O2 batteries. Possible reactions between these two solvents and Li2O2 are here discussed using X-ray photoelectron spectroscopy to analyze surface of the Li2O2 powder after direct contact with the solvents for different times of exposure. The results indicated that Li2O2 decomposes DMSO solvents, whereas no indication of degradation of MeCN by Li2O2 was observed.© 2014 The Electrochemical Society.

U2 - 10.1149/2.001403eel

DO - 10.1149/2.001403eel

M3 - Journal article

VL - 3

SP - A15-A18

JO - Electrochemical and Solid-State Letters

JF - Electrochemical and Solid-State Letters

SN - 1099-0062

T2 - 224th Electrochemical Society Meeting

Y2 - 27 October 2013 through 1 November 2013

ER -

A New Look at the Stability of Dimethyl Sulfoxide and Acetonitrile in Li-O2 Batteries

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