A generic multi-dimensional model-based system for batch cooling crystallization processes

Noor Asma Fazli Abdul Samad, Ravendra Singh, Gürkan Sin, Krist Gernaey, Rafiqul Gani

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

Highly porous deposits of flame-made aerosol nanoparticles were formed by filtration through a porous substrate (α-alumina, average pore diameter 3.7 μm). The aerosol was characterized by transmission electron microscopy (TEM) and scanning mobility particle sizer (SMPS) showing average primary and agglomerate particle sizes of 4.1 and 30 nm, respectively. The analysis of the cake structure (determination of pore-size, dec, and porosity, εc) was carried out by two non-destructive permeance methods. The first (“method I”) was based solely on the dusty gas model (DGM) for mass-transfer. Thereafter, an expression (“method II”) for the calculation of the cake porosity was derived for Knudsen numbers N10. Permeance analysis revealed poresizes (equivalent cylindrical diameter) of the deposited cakes of approximately 200 nm, independent of mass deposited (wd=0.7–36.8 mg). Calculation of the porosity by method I was prone to large errors due to any anisotropy of the porosity and resulted in unrealistically high εc values at low deposited mass (e.g. εc=0.99 at wd=0.7 mg). In contrast, the porosities (average εc=0.947–0.949) calculated by method II were independent of deposited mass and in excellent agreement to scanning electron microscopy (SEM) analysis (εc=0.94–0.97), as well as to previous studies at comparable experimental conditions (εc=0.95).
Original languageEnglish
JournalComputers & Chemical Engineering
Volume35
Issue number5
Pages (from-to)828-843
ISSN0098-1354
DOIs
Publication statusPublished - 2011

Keywords

  • Filtration
  • Morphology
  • Characterization
  • Deposition
  • Permeance measurements
  • Nanoparticles

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