A Convenient Method for Preparation of Pure Standards of Peroxyacetyl Nitrate for Atmospheric Analyses

Torben Nielsen; A. M. Hansen; E. Lund Thomsen

doi:10.1016/0004-6981(82)90134-2

A Convenient Method for Preparation of Pure Standards of Peroxyacetyl Nitrate for Atmospheric Analyses

Torben Nielsen
, A. M. Hansen
, E. Lund Thomsen

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

Peroxyacetyl nitrate (PAN) is synthesized by nitration of peracetic acid (1.2 M), extracted by n- heptane, and purified with normal-phase high-performance liquid chromatography. The purified PAN solution is free of acetyl nitrate. The content of PAN is determined by means of hydrolysis of PAN into nitrite, and determination by ion chromatography of nitrite and nitrate (formed by oxidation of nitrite). The purified PAN solution is used for the calibration of the gas Chromatograph with electron capture detection.

Original language	English
Journal	Atmospheric Environment
Volume	16
Issue number	10
Pages (from-to)	2447-2450
ISSN	1352-2310
DOIs	https://doi.org/10.1016/0004-6981(82)90134-2
Publication status	Published - 1982

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@article{89b72bc02d4041719736934951da73a5,

title = "A Convenient Method for Preparation of Pure Standards of Peroxyacetyl Nitrate for Atmospheric Analyses",

abstract = "Peroxyacetyl nitrate (PAN) is synthesized by nitration of peracetic acid (1.2 M), extracted by n- heptane, and purified with normal-phase high-performance liquid chromatography. The purified PAN solution is free of acetyl nitrate. The content of PAN is determined by means of hydrolysis of PAN into nitrite, and determination by ion chromatography of nitrite and nitrate (formed by oxidation of nitrite). The purified PAN solution is used for the calibration of the gas Chromatograph with electron capture detection.",

author = "Torben Nielsen and Hansen, \{A. M.\} and \{Lund Thomsen\}, E.",

year = "1982",

doi = "10.1016/0004-6981(82)90134-2",

language = "English",

volume = "16",

pages = "2447--2450",

journal = "Atmospheric Environment",

issn = "1352-2310",

publisher = "Elsevier",

number = "10",

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TY - JOUR

T1 - A Convenient Method for Preparation of Pure Standards of Peroxyacetyl Nitrate for Atmospheric Analyses

AU - Nielsen, Torben

AU - Hansen, A. M.

AU - Lund Thomsen, E.

PY - 1982

Y1 - 1982

N2 - Peroxyacetyl nitrate (PAN) is synthesized by nitration of peracetic acid (1.2 M), extracted by n- heptane, and purified with normal-phase high-performance liquid chromatography. The purified PAN solution is free of acetyl nitrate. The content of PAN is determined by means of hydrolysis of PAN into nitrite, and determination by ion chromatography of nitrite and nitrate (formed by oxidation of nitrite). The purified PAN solution is used for the calibration of the gas Chromatograph with electron capture detection.

AB - Peroxyacetyl nitrate (PAN) is synthesized by nitration of peracetic acid (1.2 M), extracted by n- heptane, and purified with normal-phase high-performance liquid chromatography. The purified PAN solution is free of acetyl nitrate. The content of PAN is determined by means of hydrolysis of PAN into nitrite, and determination by ion chromatography of nitrite and nitrate (formed by oxidation of nitrite). The purified PAN solution is used for the calibration of the gas Chromatograph with electron capture detection.

U2 - 10.1016/0004-6981(82)90134-2

DO - 10.1016/0004-6981(82)90134-2

M3 - Journal article

SN - 1352-2310

VL - 16

SP - 2447

EP - 2450

JO - Atmospheric Environment

JF - Atmospheric Environment

IS - 10

ER -

A Convenient Method for Preparation of Pure Standards of Peroxyacetyl Nitrate for Atmospheric Analyses

Abstract

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