4-Bromoselenoanisole

Henning Osholm Sørensen; Nicolai Stuhr-Hansen

doi:10.1107/S160053680902296X

4-Bromoselenoanisole

Henning Osholm Sørensen, Nicolai Stuhr-Hansen

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Abstract

The title compound, 1-bromo-4-methylselenobenzene, C7H7BrSe, was prepared by methylation of 4-bromoselenophenolate with methyl iodide, and crystals suitable for structure determination were obtained by sublimation. The molecule is essentially planar; the Se-Me bond is rotated by only 2.59 (19)° out of the least-squares plane of the benzene ring. The most pronounced intermolecular interactions are two hydrogen bonds of the type C-H, which determine a herring-bone pattern in the crystal packing

Original language	English
Journal	Acta Crystallographica. Section E: Structure Reports Online
Volume	E65
Issue number	7
Pages (from-to)	o1665-o1666
ISSN	1600-5368
DOIs	https://doi.org/10.1107/S160053680902296X
Publication status	Published - 2009

Keywords

Materials characterization and modelling
Materials research
AROMATIC SUBSTITUTION
SE-77 NMR

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title = "4-Bromoselenoanisole",

abstract = "The title compound, 1-bromo-4-methylselenobenzene, C7H7BrSe, was prepared by methylation of 4-bromoselenophenolate with methyl iodide, and crystals suitable for structure determination were obtained by sublimation. The molecule is essentially planar; the Se-Me bond is rotated by only 2.59 (19)° out of the least-squares plane of the benzene ring. The most pronounced intermolecular interactions are two hydrogen bonds of the type C-H, which determine a herring-bone pattern in the crystal packing",

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T1 - 4-Bromoselenoanisole

AU - Sørensen, Henning Osholm

AU - Stuhr-Hansen, Nicolai

PY - 2009

Y1 - 2009

N2 - The title compound, 1-bromo-4-methylselenobenzene, C7H7BrSe, was prepared by methylation of 4-bromoselenophenolate with methyl iodide, and crystals suitable for structure determination were obtained by sublimation. The molecule is essentially planar; the Se-Me bond is rotated by only 2.59 (19)° out of the least-squares plane of the benzene ring. The most pronounced intermolecular interactions are two hydrogen bonds of the type C-H, which determine a herring-bone pattern in the crystal packing

AB - The title compound, 1-bromo-4-methylselenobenzene, C7H7BrSe, was prepared by methylation of 4-bromoselenophenolate with methyl iodide, and crystals suitable for structure determination were obtained by sublimation. The molecule is essentially planar; the Se-Me bond is rotated by only 2.59 (19)° out of the least-squares plane of the benzene ring. The most pronounced intermolecular interactions are two hydrogen bonds of the type C-H, which determine a herring-bone pattern in the crystal packing

KW - Materials characterization and modelling

KW - Materials research

KW - AROMATIC SUBSTITUTION

KW - SE-77 NMR

KW - Materialeforskning

KW - Materialekarakterisering og materialemodellering

U2 - 10.1107/S160053680902296X

DO - 10.1107/S160053680902296X

M3 - Journal article

C2 - 21582926

SN - 1600-5368

VL - E65

SP - o1665-o1666

JO - Acta Crystallographica. Section E: Structure Reports Online

JF - Acta Crystallographica. Section E: Structure Reports Online

IS - 7

ER -

4-Bromoselenoanisole

Abstract

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