4-Bromoselenoanisole

Henning Osholm Sørensen, Nicolai Stuhr-Hansen

    Research output: Contribution to journalJournal articleResearchpeer-review

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    Abstract

    The title compound, 1-bromo-4-methylselenobenzene, C7H7BrSe, was prepared by methylation of 4-bromoselenophenolate with methyl iodide, and crystals suitable for structure determination were obtained by sublimation. The molecule is essentially planar; the Se-Me bond is rotated by only 2.59 (19)° out of the least-squares plane of the benzene ring. The most pronounced intermolecular interactions are two hydrogen bonds of the type C-H, which determine a herring-bone pattern in the crystal packing
    Original languageEnglish
    JournalActa Crystallographica. Section E: Structure Reports Online
    VolumeE65
    Issue number7
    Pages (from-to)o1665-o1666
    ISSN1600-5368
    DOIs
    Publication statusPublished - 2009

    Keywords

    • Materials characterization and modelling
    • Materials research
    • AROMATIC SUBSTITUTION
    • SE-77 NMR

    Cite this

    Sørensen, Henning Osholm ; Stuhr-Hansen, Nicolai. / 4-Bromoselenoanisole. In: Acta Crystallographica. Section E: Structure Reports Online. 2009 ; Vol. E65, No. 7. pp. o1665-o1666.
    @article{18583be805de4f8bab20f0115e2dc87b,
    title = "4-Bromoselenoanisole",
    abstract = "The title compound, 1-bromo-4-methylselenobenzene, C7H7BrSe, was prepared by methylation of 4-bromoselenophenolate with methyl iodide, and crystals suitable for structure determination were obtained by sublimation. The molecule is essentially planar; the Se-Me bond is rotated by only 2.59 (19)° out of the least-squares plane of the benzene ring. The most pronounced intermolecular interactions are two hydrogen bonds of the type C-H, which determine a herring-bone pattern in the crystal packing",
    keywords = "Materials characterization and modelling, Materials research, AROMATIC SUBSTITUTION, SE-77 NMR, Materialeforskning, Materialekarakterisering og materialemodellering",
    author = "S{\o}rensen, {Henning Osholm} and Nicolai Stuhr-Hansen",
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    4-Bromoselenoanisole. / Sørensen, Henning Osholm; Stuhr-Hansen, Nicolai.

    In: Acta Crystallographica. Section E: Structure Reports Online, Vol. E65, No. 7, 2009, p. o1665-o1666.

    Research output: Contribution to journalJournal articleResearchpeer-review

    TY - JOUR

    T1 - 4-Bromoselenoanisole

    AU - Sørensen, Henning Osholm

    AU - Stuhr-Hansen, Nicolai

    PY - 2009

    Y1 - 2009

    N2 - The title compound, 1-bromo-4-methylselenobenzene, C7H7BrSe, was prepared by methylation of 4-bromoselenophenolate with methyl iodide, and crystals suitable for structure determination were obtained by sublimation. The molecule is essentially planar; the Se-Me bond is rotated by only 2.59 (19)° out of the least-squares plane of the benzene ring. The most pronounced intermolecular interactions are two hydrogen bonds of the type C-H, which determine a herring-bone pattern in the crystal packing

    AB - The title compound, 1-bromo-4-methylselenobenzene, C7H7BrSe, was prepared by methylation of 4-bromoselenophenolate with methyl iodide, and crystals suitable for structure determination were obtained by sublimation. The molecule is essentially planar; the Se-Me bond is rotated by only 2.59 (19)° out of the least-squares plane of the benzene ring. The most pronounced intermolecular interactions are two hydrogen bonds of the type C-H, which determine a herring-bone pattern in the crystal packing

    KW - Materials characterization and modelling

    KW - Materials research

    KW - AROMATIC SUBSTITUTION

    KW - SE-77 NMR

    KW - Materialeforskning

    KW - Materialekarakterisering og materialemodellering

    U2 - 10.1107/S160053680902296X

    DO - 10.1107/S160053680902296X

    M3 - Journal article

    VL - E65

    SP - o1665-o1666

    JO - Acta Crystallographica. Section E: Structure Reports Online

    JF - Acta Crystallographica. Section E: Structure Reports Online

    SN - 1600-5368

    IS - 7

    ER -