Andrea Crovetto

2024

A phenomenological figure of merit for photovoltaic materials

Crovetto, A., 2024, In: JPhys Energy. 6, 2, 18 p., 025009.

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Monolithic Selenium/Silicon Tandem Solar Cells

Nielsen, R., Crovetto, A., Assar, A., Hansen, O., Chorkendorff, I. & Vesborg, P. C. K., 2024, In: PRX ENERGY. 3, 9 p., 013013.

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Monolithic Selenium/Silicon Tandem Solar Cells

Nielsen, R., Crovetto, A., Assar, A., Hansen, O., Chorkendorff, I. & Vesborg, P., 2024.

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Phosphosulfide semiconductors for optoelectronics and solar energy conversion

Mittmann, L. A. & Crovetto, A., 2024, In: JPhys Materials. 7, 2, 18 p., 021002.

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Understanding the light induced hydrophilicity of metal-oxide thin films

Deshpande, R. A., Navne, J., Adelmark, M. V., Shkondin, E., Crovetto, A., Hansen, O., Bachmann, J. & Taboryski, R., 2024, In: Nature Communications. 15, 1, 11 p., 124.

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2023

Is Cu_3-xP a Semiconductor, a Metal, or a Semimetal?

Crovetto, A., Unold, T. & Zakutayev, A., 2023, In: Chemistry of Materials. 35, 3, p. 1259-1272

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Phonons in Copper Diphosphide (CuP₂): Raman Spectroscopy and Lattice Dynamics Calculations

Dimitrievska, M., Litvinchuk, A. P., Zakutayev, A. & Crovetto, A., 2023, In: The Journal of Physical Chemistry Part C. 127, 22, p. 10649-10654

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The Renaissance of Selenium Thin-Film Solar Cells: The Elemental High Bandgap Photoabsorber

Nielsen, R., Hemmingsen, T., Crovetto, A., Hansen, O., Chorkendorff, I. & Vesborg, P., 2023.

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2022

(Invited) Selenium as a Top-Cell Absorber Candidate for Tandem Photoelectrochemical Stacks

Nielsen, R., Youngman, T., Crovetto, A., Seger, B., Hansen, O., Mustafa, H., Levcenco, S., Hempel, H., Olsen, T., Chorkendorff, I., Unold, T. & Vesborg, P., 2022, ECS Meeting Abstracts. The Electrochemical Society, Vol. MA2022-02. 1802

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Elemental Selenium as a Wide Bandgap Photoabsorber Appropriate for Tandem Integration with Silicon or CIGS

Nielsen, R., Youngman, T. H., Crovetto, A., Hansen, O., Chorkendorff, I. & Vesborg, P. C. K., 2022. 1 p.

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Indirect Band Gap Semiconductors for Thin-Film Photovoltaics: High-Throughput Calculation of Phonon-Assisted Absorption

Kangsabanik, J., Svendsen, M. K., Taghizadeh, A., Crovetto, A. & Thygesen, K. S., 2022, In: Journal of the American Chemical Society. 144, 43, p. 19872-19883

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2020

Assessing the defect tolerance of kesterite-inspired solar absorbersElectronic supplementary information (ESI) available: Additional figures. See DOI: 10.1039/d0ee02177f

Crovetto, A., Kim, S., Fischer, M., Stenger, N., Walsh, A., Chorkendorff, I. & Vesborg, P. C. K., 2020, In: Energy and Environmental Science. 13, 10, p. 3489-3503

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Building an All-Sulfide TaS₂/Cu₂-II-Sn-S₄/CdS Solar Cell and Putting it on Silicon

Crovetto, A., Assar, A., Nielsen, R., Hansen, O., Seger, B., Chorkendorff, I. & Vesborg, P., 2020.

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Experimental and First-Principles Spectroscopy of Cu₂SrSnS₄ and Cu₂BaSnS₄ Photoabsorbers

Crovetto, A., Xing, Z., Fischer, M., Nielsen, R., Savory, C. N., Rindzevicius, T., Stenger, N., Scanlon, D. O., Chorkendorff, I. & Vesborg, P. C. K., 2020, In: ACS Applied Materials and Interfaces. 12, 45, p. 50446-50454

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Monolithic thin-film chalcogenide–silicon tandem solar cells enabled by a diffusion barrier

Hajijafarassar, A., Martinho, F. M. A., Stulen, F., Grini, S., Mariño, S. L., Espindola Rodriguez, M., Döbeli, M., Canulescu, S., Stamate, E., Gansukh, M., Engberg, S. L. J., Crovetto, A., Vines, L., Schou, J. & Hansen, O., 2020, In: Solar Energy Materials and Solar Cells. 207, 11 p., 110334.

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Nitride-based interfacial layers for monolithic tandem integration of new solar energy materials on Si: The case of CZTS

Martinho, F. M. A., Hajijafarassar, A., Mariño, S. L., Espindola Rodriguez, M., Engberg, S. L. J., Gansukh, M., Stulen, F., Grini, S., Canulescu, S., Stamate, E., Crovetto, A., Vines, L., Schou, J. & Hansen, O., 2020, In: Applied Energy Materials. 3, 5, p. 4600–4609

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Parallel evaluation of the BiI₃, BiOI, and Ag₃BiI₆ layered photoabsorbers

Crovetto, A., Hajijafarassar, A., Hansen, O., Seger, B., Chorkendorff, I. & Vesborg, P. C. K., 2020, In: Chemistry of Materials. 32, 8, p. 3385-3395

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Resonant x-ray ptychographic nanotomography of kesterite solar cells

Fevola, G., Jørgensen, P. S., Verezhak, M., Slyamov, A., Crovetto, A., Balogh, Z. I., Rein, C., Canulescu, S. & Andreasen, J. W., 2020, In: Physical Review Research. 2, 1, 12 p., 013378.

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TaS₂ back contact improving oxide-converted Cu₂BaSnS₄ solar cells

Crovetto, A., Børsting, K., Nielsen, R., Hajijafarassar, A., Hansen, O., Seger, B., Chorkendorff, I. & Vesborg, P. C. K., 2020, In: Applied Energy Materials. 3, 1, p. 1190-1198

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2019

A universal approach for the synthesis of two-dimensional binary compounds

Shivayogimath, A., Thomsen, J. D., Mackenzie, D. M. A., Geisler, M., Stan, R.-M., Holt, A. J., Bianchi, M., Crovetto, A., Whelan, P. R., Carvalho, A., Neto, A. H. C., Hofmann, P., Stenger, N., Bøggild, P. & Booth, T. J., 2019, In: Nature Communications. 10, 1, 7 p., 2957.

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Building an All-Sulfide TaS₂/Cu₂-II-Sn-S₄/CdS Solar Cell and Putting it on Silicon

Crovetto, A., Hajijafarassar, A., Nielsen, R., Hansen, O., Seger, B., Chorkendorff, I. & Vesborg, P., 2019, p. 161-161.

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CZTS solar cells absorbers produced by sputtering or pulsed laser deposition

Schou, J., Gansukh, M., Martinho, F. M. A., Mariño, S. L., Espindola Rodriguez, M., Hajijafarassar, A., Stamate, E., Engberg, S. L. J., Crovetto, A., Canulescu, S. & Hansen, O., 2019.

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Monolithic Cu₂ZnSnS₄-on-Silicon Tandem Solar Cells Enabled by a Diffusion Barrier

Hajijafarassar, A., Martinho, F., Stulen, F., Grini, S., López-Mariño, S., Espindola-Rodriguez, M., Canulescu, S., Stamate, E., Gansukh, M., Engberg, S., Crovetto, A., Vines, L., Schou, J. & Hansen, O., 2019.

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Monolithic CZTS-on-Silicon Tandem Solar Cells: Prospects and Challenges

Hajijafarassar, A., Martinho, F., Shearer, D., Crovetto, A., Canulescu, S., Iandolo, B., Gansukh, M., López Mariño, S., Espindola Rodriguez, M., Engberg, S. L. J., Schou, J. & Hansen, O., 2019.

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Monolithic Thin-Film Chalcogenide-Silicon Tandem Solar Cells Enabled by a Diffusion Barrier

Hajijafarassar, A., Martinho, F., Crovetto, A., Schou, J. & Hansen, O., 2019, p. 672-672.

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Shining Light on Sulﬁde Perovskites: LaYS₃ Material Properties and Solar Cells

Crovetto, A., Nielsen, R., Pandey, M., Watts, L., Labram, J. G., Geisler, M., Stenger, N., Jacobsen, K. W., Hansen, O., Seger, B., Chorkendorff, I. & Vesborg, P. C. K., 2019, In: Chemistry of Materials. 31, 9, p. 3359-3369 11 p.

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Wide Band Gap Cu₂SrSnS₄Solar Cells from Oxide Precursors

Crovetto, A., Nielsen, R., Stamate, E., Hansen, O., Seger, B., Chorkendorff, I. & Vesborg, P. C. K., 2019, In: Applied Energy Materials. 2, 10, p. 7340-7344 5 p.

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2018

Assessment of the photovoltaic properties of CZTS grown on representative Si solar cell structures for monolithic CZTS/Si tandem applications

Martinho, F., Hajijafarassar, A., López-Mariño, S., Espindola Rodriguez, M., Canulescu, S., Stamate, E., Gansukh, M., Engberg, S., Crovetto, A., Hansen, O. & Schou, J., 2018.

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Estimating complete band diagrams of non-ideal heterointerfaces by combining ellipsometry and photoemission spectroscopy

Crovetto, A., 2018, In: Journal of Applied Physics. 124, 8, 7 p.

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Investigation of Ti-based barrier layers for application in monolithic Silicon-Chalcogenide tandem solar cells

Hajijafarassar, A., Martinho, F., Grini, S., Arnesen Stulen, F., Vines, L., Shearer, D., Döbeli, M., Crovetto, A., López-Mariño, S., Canulescu, S., Schou, J. & Hansen, O., 2018.

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Large process-dependent variations in band alignment and interface band gaps of Cu₂ZnSnS₄/CdS solar cells

Crovetto, A., Cazzaniga, A., Ettlinger, R. B., Schou, J. & Hansen, O., 2018, In: Solar Energy Materials and Solar Cells. 187, p. 233-240

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Non-destructive Thickness Mapping of Wafer-Scale Hexagonal Boron Nitride Down to a Monolayer

Crovetto, A., Whelan, P. R., Wang, R., Galbiati, M., Hofmann, S. & Camilli, L., 2018, In: A C S Applied Materials and Interfaces. 10, p. 25804−25810

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2017

Boosting the Open Circuit Voltage of Cu₂ZnSnS₄ Solar Cells by a Lattice-Matched CeO₂ Layer and Theoretical Understanding of Interface Defects

Crovetto, A., Yan, C., Palsgaard, M. L. N., Iandolo, B., Zhou, F., Gunst, T., Markussen, T., Stride, J., Schou, J., Stokbro, K., Brandbyge, M., Hao, X. & Hansen, O., 2017.

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How the relative permittivity of solar cell materials influences solar cell performance

Crovetto, A., Huss-Hansen, M. K. & Hansen, O., 2017, In: Solar Energy. 149, p. 145-150 6 p.

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Interface band gap narrowing behind open circuit voltage losses in Cu₂ZnSnS₄ solar cells

Crovetto, A., Palsgaard, M. L. N., Gunst, T., Markussen, T., Stokbro, K., Brandbyge, M. & Hansen, O., 2017, In: Applied Physics Letters. 110, 4 p., 083903.

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Investigation of Cu₂ZnSnS₄ nanoparticles for thin-film solar cell applications

Engberg, S. L. J., Agersted, K., Crovetto, A., Hansen, O., Lam, Y. M. & Schou, J., 2017, In: Thin Solid Films. 628, p. 163-169 7 p.

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Na-assisted grain growth in CZTS nanoparticle thin films for solar cell applications

Engberg, S. L. J., Crovetto, A., Hansen, O., Lam, Y. M. & Schou, J., 2017. 1 p.

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Pulsed laser deposition (PLD) of the CZTS absorber for thin solar cells with up to 5.2-% -efficiency

Cazzaniga, A. C., Crovetto, A., Ettlinger, R. B., Canulescu, S., Canulescu, S., Pryds, N., Yan, C., Sun, K., Hao, X., Hansen, O. & Schou, J., 2017. 1 p.

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Pulsed laser deposition (PLD) of the CZTS absorber for thin solar cells with up to 5.2-% -efficiency

Cazzaniga, A. C., Canulescu, S., Ettlinger, R. B., Pryds, N., Hansen, O., Schou, J., Crovetto, A., Hansen, O., Yan, C., Sun, K. & Hao, X., 2017. 1 p.

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Sulfide perovskites for solar energy conversion applications: computational screening and synthesis of the selected compound LaYS₃

Kuhar, K., Crovetto, A., Pandey, M., Thygesen, K. S., Seger, B., Vesborg, P. C. K., Hansen, O., Chorkendorff, I. & Jacobsen, K. W., 2017, In: Energy & Environmental Science. 10, 12, p. 2579-2593 15 p.

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Surface passivation and carrier selectivity of the thermal-atomic-layer-deposited TiO₂ on crystalline silicon

Plakhotnyuk, M., Schüler, N., Shkondin, E., Vijayan, R. A., Masilamani, S., Varadharajaperumal, M., Crovetto, A. & Hansen, O., 2017, In: Japanese Journal of Applied Physics. 56, 8S2, 8 p., 08MA11.

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Sustainable solar fuels and electricity through discovery and prototyping of new materials

Crovetto, A., Kuhar, K., Pandey, M., Thygesen, K. S., Jacobsen, K. W., Hansen, O., Seger, B., Vesborg, P. C. K. & Chorkendorff, I., 2017, Book of Abstracts, Sustain 2017. Technical University of Denmark, 1 p. M-1

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Technology for Si/CZTS Tandem Solar Cell

Hajijafarassar, A., Crovetto, A., Pedersen, T., Mariño, S. L., Schou, J. & Hansen, O., 2017, Book of Abstracts, Sustain 2017. Technical University of Denmark, 1 p. M-17

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Temperature dependent photoreflectance study of Cu2SnS3 thin films produced by pulsed laser deposition

Raadik, T., Grossberg, M., Krustok, J., Kauk-Kuusik, M., Crovetto, A., Ettlinger, R. B., Hansen, O. & Schou, J., 2017, In: Applied Physics Letters. 110, 26, 4 p., 261105.

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The effect of dopants on grain growth and PL in CZTS nanoparticle thin films for solar cell applications

Engberg, S. L. J., Crovetto, A., Hansen, O. & Schou, J., 2017. 1 p.

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Ultra-thin Cu2ZnSnS4 solar cell by pulsed laser deposition

Cazzaniga, A. C., Crovetto, A., Yan, C., Sun, K., Hao, X., Estelrich, J. R., Canulescu, S., Stamate, E., Pryds, N., Hansen, O. & Schou, J., 2017, In: Solar Energy Materials & Solar Cells. 166, p. 91–99

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What is the band alignment of Cu₂ZnSn(S,Se)₄ solar cells?

Crovetto, A. & Hansen, O., 2017, In: Solar Energy Materials and Solar Cells. 169, p. 177-194 18 p.

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2016

Al-doped ZnO: RF- or DC-sputtering?

Crovetto, A., Ottsen, T., Stamate, E., Kjær, D., Schou, J. & Hansen, O., 2016. 1 p.

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Behind the Nature of Titanium Oxide Excellent Surface Passivation and Carrier Selectivity of c-Si

Plakhotnyuk, M., Crovetto, A. & Hansen, O., 2016. 3 p.

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Bi-resonant structure with piezoelectric PVDF films for energy harvesting from random vibration sources at low frequency

Liang, S., Crovetto, A., Peng, Z., Zhang, A., Hansen, O., Wang, M., Li, X. & Wang, F., 2016, In: Sensors and Actuators A: Physical. 247, p. 547-554

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Andrea Crovetto

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