Universal Brønsted-Evans-Polanyi Relations for C–C, C–O, C–N, N–O, N–N, and O–O Dissociation Reactions

Publication: Research - peer-reviewJournal article – Annual report year: 2011

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It is shown that for all the essential bond forming and bond breaking reactions on metal surfaces, the reactivity of the metal surface correlates linearly with the reaction energy in a single universal relation. Such correlations provide an easy way of establishing trends in reactivity among the different transition metals.
Original languageEnglish
JournalCatalysis Letters
Publication date2011
Volume141
Issue3
Pages370-373
ISSN1011-372X
DOIs
StatePublished
CitationsWeb of Science® Times Cited: 39

Keywords

  • Coupling reactions, Stepped surfaces, Density functional theory, BEP relations, Scaling relations, Bond breaking reactions
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