Thermodynamic assessment of the CoOx-CrO1.5 system

Publication: Research - peer-reviewJournal article – Annual report year: 2009

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By application of the CALPHAD method, a consistent set of thermodynamic model parameters is optimized for the oxide phases in the Co–Cr–O system. Cobalt chromium spinel is described as a normal spinel at room temperature and with cation redistribution at high temperature. All the solid oxide solution phases are described using the compound energy model, and the liquid phase is described using the two-sublattice model for ionic liquids. Calculated phase diagrams are presented, and values for the thermodynamic properties are compared with experimental data.
Original languageEnglish
JournalJournal of Alloys and Compounds
Publication date2009
Volume485
Issue1-2
Pages427-434
ISSN0925-8388
DOIs
StatePublished
CitationsWeb of Science® Times Cited: 2

Keywords

  • Solid Oxide Fuel Cells, Fuel Cells and hydrogen
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