Tetrapotassium cis-dioxido-trans-bis(sulfato-kappa O)sulfato(kappa O-2,O ')molybdate(VI)

Publication: Research - peer-reviewJournal article – Annual report year: 2008

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The title compound, K-4[(MoO2)-O-VI(SO4)(3)], was precipitated from a melt of molybdenum(VI) oxide and potassium sulfate in potassium disulfate. The compound contains monomeric [(MoO2)-O-VI(SO4)(3)](4-) anions, with the Mo-VI atom, both oxide ligands, and the S atom and both ligating O atoms of the bidentate sulfate group lying on a crystallographic mirror plane. One of the potassium cations is nine-coordinate, while the other is eight-coordinate.
Original languageEnglish
JournalActa Crystallographica. Section E: Structure Reports Online
Publication date2008
Volume64
Issue3
PagesI20-U40
ISSN1600-5368
DOIs
StatePublished
CitationsWeb of Science® Times Cited: 2
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