Tetrapotassium cis-dioxido-trans-bis(sulfato-kappa O)sulfato(kappa O-2,O ')molybdate(VI)
Publication: Research - peer-review › Journal article – Annual report year: 2008
The title compound, K-4[(MoO2)-O-VI(SO4)(3)], was precipitated from a melt of molybdenum(VI) oxide and potassium sulfate in potassium disulfate. The compound contains monomeric [(MoO2)-O-VI(SO4)(3)](4-) anions, with the Mo-VI atom, both oxide ligands, and the S atom and both ligating O atoms of the bidentate sulfate group lying on a crystallographic mirror plane. One of the potassium cations is nine-coordinate, while the other is eight-coordinate.
| Original language | English |
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| Journal | Acta Crystallographica. Section E: Structure Reports Online |
| Volume | 64 |
| Issue number | 3 |
| Pages (from-to) | I20-U40 |
| ISSN | 1600-5368 |
| DOIs | |
| State | Published - 2008 |
| Citations | Web of Science® Times Cited: 3 |
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