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An efficient and broadly applicable alternative to the classical Pictet–Spengler synthesis of tetrahydro-β-carbolines is presented. The method relies on metal-catalyzed isomerization of allylic amines to form reactive iminium intermediates which can be trapped by a tethered indole nucleophile.
Original languageEnglish
JournalChemical Communications
Publication date2012
Volume48
Issue27
Pages3345-3347
ISSN1359-7345
DOIs
StatePublished

Bibliographical note

Electronic supplementary information (ESI) available: Experimental procedures, characterization data for all substrates and products. See DOI: 10.1039/c2cc17704h

CitationsWeb of Science® Times Cited: 11
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