Mechanical properties of low-density polyethylene filled by graphite nanoplatelets
Publication: Research - peer-review › Journal article – Annual report year: 2012
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Mechanical properties of low-density polyethylene filled by graphite nanoplatelets. / Carotenuto, G.; De Nicola, S.; Palomba, M.; Pullini, D.; Horsewell, A.; Hansen, Thomas Willum; Nicolais, L.
In: Nanotechnology, Vol. 23, No. 48, 2012, p. 485705.Publication: Research - peer-review › Journal article – Annual report year: 2012
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TY - JOUR
T1 - Mechanical properties of low-density polyethylene filled by graphite nanoplatelets
A1 - Carotenuto,G.
A1 - De Nicola,S.
A1 - Palomba,M.
A1 - Pullini,D.
A1 - Horsewell,A.
A1 - Hansen,Thomas Willum
A1 - Nicolais,L.
AU - Carotenuto,G.
AU - De Nicola,S.
AU - Palomba,M.
AU - Pullini,D.
AU - Horsewell,A.
AU - Hansen,Thomas Willum
AU - Nicolais,L.
PB - Institute of Physics Publishing
PY - 2012
Y1 - 2012
N2 - The mechanical properties of GNP/LDPE nanocomposites (graphite nanoplatelets/low density polyethylene) have been investigated, in order to establish the effect of nanoscale reinforcement within the polymer matrix. Results show that the presence of the filler does not involve a change in the microscopic structure of the polymer. However, on a macroscopic scale, GNPs limit the mobility of the polymer chains, resulting in an increase in stiffness for the final composite. Orientation of GNPs within the LDPE matrix is also an important issue that affects mechanical properties and it has been evaluated by testing nanocomposites made by different manufacturing techniques (compression moulding and blown extrusion). The comparison between the experimental data and the Halpin–Tsai model shows that the orientation of GNPs due to the extrusion process leads to values of tensile modulus higher than that obtained with the randomly oriented disposition resulting from the compression moulding technique.
AB - The mechanical properties of GNP/LDPE nanocomposites (graphite nanoplatelets/low density polyethylene) have been investigated, in order to establish the effect of nanoscale reinforcement within the polymer matrix. Results show that the presence of the filler does not involve a change in the microscopic structure of the polymer. However, on a macroscopic scale, GNPs limit the mobility of the polymer chains, resulting in an increase in stiffness for the final composite. Orientation of GNPs within the LDPE matrix is also an important issue that affects mechanical properties and it has been evaluated by testing nanocomposites made by different manufacturing techniques (compression moulding and blown extrusion). The comparison between the experimental data and the Halpin–Tsai model shows that the orientation of GNPs due to the extrusion process leads to values of tensile modulus higher than that obtained with the randomly oriented disposition resulting from the compression moulding technique.
U2 - 10.1088/0957-4484/23/48/485705
DO - 10.1088/0957-4484/23/48/485705
JO - Nanotechnology
JF - Nanotechnology
SN - 0957-4484
IS - 48
VL - 23
SP - 485705
ER -