Line widths in nitroxides

Publication: Research - peer-reviewJournal article – Annual report year: 1996

Without internal affiliation

  • Author: Radner, Finn

  • Author: Hersvall, Carl Johan

    Nycomed Innovation AB

  • Author: Rassat, André

    Centre National de la Recherche Scientifique

  • Author: Ardenkjær-Larsen, Jan Henrik

    Unknown

  • Author: Gambarelli, Serge

    Centre National de la Recherche Scientifique

  • Author: Jaouen, Daniel

    Centre National de la Recherche Scientifique

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The 2,5-di-tert-butyl-3,4-dimethoxycarbonyl-pyrryloxyl radical has the small est line-width and the smallest nitrogen hyperfine splitting reported for a stable nitroxide. The influence of long range proton splittings was shown by selective and total deuteriation. As expected on theoretical grounds, line widths and nitrogen hyperfine splitting are correlated.
Original languageEnglish
JournalResearch on Chemical Intermediates
Volume22
Issue number5
Pages (from-to)417-425
ISSN0922-6168
DOIs
StatePublished - 1996
Peer-reviewedYes
CitationsWeb of Science® Times Cited: 3
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