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Influence of oxide and alloy formation on the Electrochemistry of Ti deposition from the NaCl-KCl-NaF-K-2 TiF6 melt reduced by metallic Ti. / Barner, Jens H. Von; Precht Noyé, Pernille; Barhoun, A; Lantelme, Frederic.

In: Electrochemical Society. Journal, Vol. 152, No. 1, 2005, p. C20-C26.

Publication: Research - peer-reviewJournal article – Annual report year: 2005

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Barner, Jens H. Von; Precht Noyé, Pernille; Barhoun, A; Lantelme, Frederic / Influence of oxide and alloy formation on the Electrochemistry of Ti deposition from the NaCl-KCl-NaF-K-2 TiF6 melt reduced by metallic Ti.

In: Electrochemical Society. Journal, Vol. 152, No. 1, 2005, p. C20-C26.

Publication: Research - peer-reviewJournal article – Annual report year: 2005

Bibtex

@article{bccf4fc32b474f0286b1feb20937d513,
title = "Influence of oxide and alloy formation on the Electrochemistry of Ti deposition from the NaCl-KCl-NaF-K-2 TiF6 melt reduced by metallic Ti",
publisher = "Electrochemical Society, Inc.",
author = "Barner, {Jens H. Von} and {Precht Noyé}, Pernille and A Barhoun and Frederic Lantelme",
note = "Copyright The Electrochemical Society, Inc. [2005]. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS).",
year = "2005",
doi = "10.1149/1.1833313",
volume = "152",
number = "1",
pages = "C20--C26",
journal = "Electrochemical Society. Journal",
issn = "0013-4651",

}

RIS

TY - JOUR

T1 - Influence of oxide and alloy formation on the Electrochemistry of Ti deposition from the NaCl-KCl-NaF-K-2 TiF6 melt reduced by metallic Ti

A1 - Barner,Jens H. Von

A1 - Precht Noyé,Pernille

A1 - Barhoun,A

A1 - Lantelme,Frederic

AU - Barner,Jens H. Von

AU - Precht Noyé,Pernille

AU - Barhoun,A

AU - Lantelme,Frederic

PB - Electrochemical Society, Inc.

PY - 2005

Y1 - 2005

N2 - The redox reactions in KCl-NaCl-NaF-K2TiF6 melts reduced by titanium metal have been studied by cyclic voltammetry and chronopotentiommetry. At platinum and nickel electrodes waves due to alloy formation were seen preceding the Ti(III) --> Ti metal deposition wave. The presence of oxide species could be detected as waves on voltammograms performed with platinum electrodes. Deposits on nickel plates in general consisted of multiphase Ni-Ti layers. By varying the deposition potential outer layers with compositions ranging from pure titanium over NiTi to nickel-rich alloys such as Ni3Ti could be obtained. Pulse plating produced the best titanium coating. With constant potential electrolyses it was also possible to deposit titanium diboride coatings of high quality from the mixed chloride-fluoride melts. (C) 2004 The Electrochemical Society.

AB - The redox reactions in KCl-NaCl-NaF-K2TiF6 melts reduced by titanium metal have been studied by cyclic voltammetry and chronopotentiommetry. At platinum and nickel electrodes waves due to alloy formation were seen preceding the Ti(III) --> Ti metal deposition wave. The presence of oxide species could be detected as waves on voltammograms performed with platinum electrodes. Deposits on nickel plates in general consisted of multiphase Ni-Ti layers. By varying the deposition potential outer layers with compositions ranging from pure titanium over NiTi to nickel-rich alloys such as Ni3Ti could be obtained. Pulse plating produced the best titanium coating. With constant potential electrolyses it was also possible to deposit titanium diboride coatings of high quality from the mixed chloride-fluoride melts. (C) 2004 The Electrochemical Society.

UR - http://dx.doi.org/10.1149/1.1833313

U2 - 10.1149/1.1833313

DO - 10.1149/1.1833313

JO - Electrochemical Society. Journal

JF - Electrochemical Society. Journal

SN - 0013-4651

IS - 1

VL - 152

SP - C20-C26

ER -