High-resolution rovibrational analysis of CH281BrF in the range 920–980cm−1

Publication: Research - peer-reviewJournal article – Annual report year: 2013

  • Author: Visinoni, R.

    Universitá Ca' Foscari Venezia, Italy

  • Author: Baldacci, A.

    Universitá Ca' Foscari Venezia, Italy

  • Author: Stoppa, P.

    Universitá Ca' Foscari Venezia, Italy

  • Author: Kollipost, F.

    Georg-August-Universität Göttingen, Germany

  • Author: Larsen, René Wugt

    Department of Chemistry, Technical University of Denmark, Kemitorvet, 2800, Kgs. Lyngby, Denmark

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The high-resolution infrared spectrum of CH281BrF has been studied in part of the atmospheric window between 920 and 980cm−1, the region characterized by the v9 and v5+v6 absorptions. The v9 emerges as a pseudo a-type band, with selection rule ΔKa=ΔKc=0, ±2, and v5+v6 exhibits a predominant a-type structure. The interactions connecting these levels and the dark 3v6 state have been explored. The anomalous v9 transitions have been ascribed to Coriolis interaction with v4. The analysis yields a set of accurate upper-state parameters for v9 and v5+v6. Spectroscopic information on 3v6 has been also obtained.
Original languageEnglish
JournalChemical Physics Letters
Volume579
Pages (from-to)16-22
ISSN0009-2614
DOIs
StatePublished - 2013
CitationsWeb of Science® Times Cited: 1
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