Determination of Core-Shell Structures in Pd-Hg Nanoparticles by STEM-EDX

Research output: Research - peer-reviewJournal article – Annual report year: 2015

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The structural and elemental configuration of a high-performing Pd-Hg electrocatalyst for oxygen reduction to hydrogen peroxide has been studied by means of high-resolution scanning transmission electron microscopy. Pd-Hg nanoparticles are shown to have a crystalline core-shell structure, with a Pd core and a Pd-Hg ordered alloy shell. The ordered shell is responsible for the high oxygen reduction selectivity to H2O2.
Original languageEnglish
JournalChemcatchem
Volume7
Issue number22
Pages (from-to)3748-3752
Number of pages5
ISSN1867-3880
DOIs
StatePublished - 2015
CitationsWeb of Science® Times Cited: 2
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