Degadation of semiconducting polymers by concentrated sunlight

Publication: Research - peer-reviewJournal article – Annual report year: 2010

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A lens based sunlight concentration setup was used to accelerate the degradation of semiconducting polymers. Sunlight was collected outdoor and focused into an optical fiber bundle allowing for indoor experimental work. Photo-degradation of several polymers was studied by UV–vis absorbance spectroscopy and infra-red spectroscopy. This showed that the degradation rate is significantly increased by increasing illumination intensity. Acceleration factors exceeding 100 compared to standard 1 sun illumination were observed for solar concentration of 200 suns in the case of P3HT. A comparison between infra-red spectra of MEH-PPV degraded at 1 sun intensity and at high solar concentration only showed minor deviations in degradation mechanisms. The acceleration factor was found to vary linearly with the solar concentration. Finally, a comparison of the degradation rates at 1 sun and 100 suns was carried out in a materials study employing five different conjugated polymers relevant to polymer solar cells for which acceleration factors in the range 19–55 were obtained.
Original languageEnglish
JournalSolar Energy Materials & Solar Cells
Publication date2011
Volume95
Issue5
Pages1308-1314
ISSN0927-0248
DOIs
StatePublished

Bibliographical note

This work was supported by the Danish Strategic Research Council (DSF2104-
05-0052 and 2104-07-0022), EUDP (j.nr.64009-0050) and
PV-ERA-NET (project acronym POLYSTAR).

CitationsWeb of Science® Times Cited: 19

Keywords

  • Polymer solar cells, Solar energy
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