Cover Picture: Metal‐Free Dehydration of Glucose to 5‐(Hydroxymethyl)furfural in Ionic Liquids with Boric Acid as a Promoter (Chem. Eur. J. 5/2011)

Publication: Research - peer-review › Journal article – Annual report year: 2011

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Cover Picture: Metal‐Free Dehydration of Glucose to 5‐(Hydroxymethyl)furfural in Ionic Liquids with Boric Acid as a Promoter (Chem. Eur. J. 5/2011). / Ståhlberg, Tim Johannes Bjarki ; Rodriguez, Sergio ; Fristrup, Peter ; Riisager, Anders.

In: Chemistry: A European Journal, Vol. 17, No. 5, 2011, p. 1369.

Publication: Research - peer-review › Journal article – Annual report year: 2011

In: Chemistry: A European Journal, Vol. 17, No. 5, 2011, p. 1369.

Publication: Research - peer-review › Journal article – Annual report year: 2011

Bibtex

@article{b3b9b703cf6d4fcebaaaf18cac17c4f6,

title = "Cover Picture: Metal‐Free Dehydration of Glucose to 5‐(Hydroxymethyl)furfural in Ionic Liquids with Boric Acid as a Promoter (Chem. Eur. J. 5/2011)",

publisher = "Wiley - V C H Verlag GmbH & Co. KGaA",

author = "Ståhlberg, {Tim Johannes Bjarki} and Sergio Rodriguez and Peter Fristrup and Anders Riisager",

year = "2011",

volume = "17",

number = "5",

pages = "1369",

journal = "Chemistry: A European Journal",

issn = "0947-6539",

}

RIS

TY - JOUR

T1 - Cover Picture: Metal‐Free Dehydration of Glucose to 5‐(Hydroxymethyl)furfural in Ionic Liquids with Boric Acid as a Promoter (Chem. Eur. J. 5/2011)

A1 - Ståhlberg,Tim Johannes Bjarki

A1 - Rodriguez,Sergio

A1 - Fristrup,Peter

A1 - Riisager,Anders

AU - Ståhlberg,Tim Johannes Bjarki

AU - Rodriguez,Sergio

AU - Fristrup,Peter

AU - Riisager,Anders

PB - Wiley - V C H Verlag GmbH & Co. KGaA

PY - 2011

Y1 - 2011

N2 - Boric acid promotes the dehydration of glucose to 5-(hydroxy)methylfurfural in ionic liquids. Computational analyses by DFT calculations show a significant decrease in energy for the isomerization of glucose to fructose when the sugars are bound to boric acid and isotopic labeling NMR studies confirm that the mechanism proceeds via an ene–diol intermediate as described by A. Riisager, P. Fristrup et al. in their Full Paper on page 1456 ff.

AB - Boric acid promotes the dehydration of glucose to 5-(hydroxy)methylfurfural in ionic liquids. Computational analyses by DFT calculations show a significant decrease in energy for the isomerization of glucose to fructose when the sugars are bound to boric acid and isotopic labeling NMR studies confirm that the mechanism proceeds via an ene–diol intermediate as described by A. Riisager, P. Fristrup et al. in their Full Paper on page 1456 ff.

U2 - 10.1002/chem.201190018

DO - 10.1002/chem.201190018

JO - Chemistry: A European Journal

JF - Chemistry: A European Journal

SN - 0947-6539

IS - 5

VL - 17

SP - 1369

ER -